Hexa­kis­(dimethyl­formamide-κO)manganese(II) μ-oxido-bis­[trichlorido­ferrate(III)]

The title compound, [Mn(C(3)H(7)NO)(6)][Fe(2)Cl(6)O], was obtained unintentionally as a product of an attempted synthesis of heterometallic complexes with Schiff base ligands using manganese powder and FeCl(3)·6H(2)O as starting materials. In the [Fe(2)OCl(6)](2−) anion, the O atom and the Fe atom o...

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Autores principales: Chygorin, Eduard N., Petrusenko, Svitlana R., Kokozay, Volodymyr N., Smal, Yuri O., Omelchenko, Irina V., Shishkin, Oleg V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246982/
https://www.ncbi.nlm.nih.gov/pubmed/22219802
http://dx.doi.org/10.1107/S1600536811041523
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author Chygorin, Eduard N.
Petrusenko, Svitlana R.
Kokozay, Volodymyr N.
Smal, Yuri O.
Omelchenko, Irina V.
Shishkin, Oleg V.
author_facet Chygorin, Eduard N.
Petrusenko, Svitlana R.
Kokozay, Volodymyr N.
Smal, Yuri O.
Omelchenko, Irina V.
Shishkin, Oleg V.
author_sort Chygorin, Eduard N.
collection PubMed
description The title compound, [Mn(C(3)H(7)NO)(6)][Fe(2)Cl(6)O], was obtained unintentionally as a product of an attempted synthesis of heterometallic complexes with Schiff base ligands using manganese powder and FeCl(3)·6H(2)O as starting materials. In the [Fe(2)OCl(6)](2−) anion, the O atom and the Fe atom occupy positions with site symmetry [Image: see text] and 3, respectively, resulting in a linear Fe—O—Fe angle and a staggered conformation. The octa­hedrally surrounded cation (site symmetry [Image: see text]) and the [Fe(2)Cl(6)O](2−) anion are alternately stacked along [001].
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spelling pubmed-32469822012-01-04 Hexa­kis­(dimethyl­formamide-κO)manganese(II) μ-oxido-bis­[trichlorido­ferrate(III)] Chygorin, Eduard N. Petrusenko, Svitlana R. Kokozay, Volodymyr N. Smal, Yuri O. Omelchenko, Irina V. Shishkin, Oleg V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(C(3)H(7)NO)(6)][Fe(2)Cl(6)O], was obtained unintentionally as a product of an attempted synthesis of heterometallic complexes with Schiff base ligands using manganese powder and FeCl(3)·6H(2)O as starting materials. In the [Fe(2)OCl(6)](2−) anion, the O atom and the Fe atom occupy positions with site symmetry [Image: see text] and 3, respectively, resulting in a linear Fe—O—Fe angle and a staggered conformation. The octa­hedrally surrounded cation (site symmetry [Image: see text]) and the [Fe(2)Cl(6)O](2−) anion are alternately stacked along [001]. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246982/ /pubmed/22219802 http://dx.doi.org/10.1107/S1600536811041523 Text en © Chygorin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chygorin, Eduard N.
Petrusenko, Svitlana R.
Kokozay, Volodymyr N.
Smal, Yuri O.
Omelchenko, Irina V.
Shishkin, Oleg V.
Hexa­kis­(dimethyl­formamide-κO)manganese(II) μ-oxido-bis­[trichlorido­ferrate(III)]
title Hexa­kis­(dimethyl­formamide-κO)manganese(II) μ-oxido-bis­[trichlorido­ferrate(III)]
title_full Hexa­kis­(dimethyl­formamide-κO)manganese(II) μ-oxido-bis­[trichlorido­ferrate(III)]
title_fullStr Hexa­kis­(dimethyl­formamide-κO)manganese(II) μ-oxido-bis­[trichlorido­ferrate(III)]
title_full_unstemmed Hexa­kis­(dimethyl­formamide-κO)manganese(II) μ-oxido-bis­[trichlorido­ferrate(III)]
title_short Hexa­kis­(dimethyl­formamide-κO)manganese(II) μ-oxido-bis­[trichlorido­ferrate(III)]
title_sort hexa­kis­(dimethyl­formamide-κo)manganese(ii) μ-oxido-bis­[trichlorido­ferrate(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246982/
https://www.ncbi.nlm.nih.gov/pubmed/22219802
http://dx.doi.org/10.1107/S1600536811041523
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