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Tetra-μ-2-methylbenzoato-κ(8) O:O′-bis[(ethanol-κO)copper(II)]
In the title dinuclear complex, [Cu(2)(C(8)H(7)O(2))(4)(C(2)H(5)OH)(2)], four 2-methylbenzoato anions form a cage around two Cu(II) ions in a syn–anti configuration. Two ethanol molecules coordinate the Cu atoms in apical positions, giving an overall square-pyramidal coordination geometry. The Cu⋯...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246983/ https://www.ncbi.nlm.nih.gov/pubmed/22219803 http://dx.doi.org/10.1107/S1600536811042322 |
| _version_ | 1782220019027935232 |
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| author | Ni, Sheng-Liang Yu, Jie-Lian Wang, Yuan-Ling Lin, Jian-Li |
| author_facet | Ni, Sheng-Liang Yu, Jie-Lian Wang, Yuan-Ling Lin, Jian-Li |
| author_sort | Ni, Sheng-Liang |
| collection | PubMed |
| description | In the title dinuclear complex, [Cu(2)(C(8)H(7)O(2))(4)(C(2)H(5)OH)(2)], four 2-methylbenzoato anions form a cage around two Cu(II) ions in a syn–anti configuration. Two ethanol molecules coordinate the Cu atoms in apical positions, giving an overall square-pyramidal coordination geometry. The Cu⋯Cu separation is 2.600 (1) Å. In the crystal, molecules are assembled into chains extending in [001] through O—H⋯O hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3246983 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32469832012-01-04 Tetra-μ-2-methylbenzoato-κ(8) O:O′-bis[(ethanol-κO)copper(II)] Ni, Sheng-Liang Yu, Jie-Lian Wang, Yuan-Ling Lin, Jian-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear complex, [Cu(2)(C(8)H(7)O(2))(4)(C(2)H(5)OH)(2)], four 2-methylbenzoato anions form a cage around two Cu(II) ions in a syn–anti configuration. Two ethanol molecules coordinate the Cu atoms in apical positions, giving an overall square-pyramidal coordination geometry. The Cu⋯Cu separation is 2.600 (1) Å. In the crystal, molecules are assembled into chains extending in [001] through O—H⋯O hydrogen bonds. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246983/ /pubmed/22219803 http://dx.doi.org/10.1107/S1600536811042322 Text en © Ni et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ni, Sheng-Liang Yu, Jie-Lian Wang, Yuan-Ling Lin, Jian-Li Tetra-μ-2-methylbenzoato-κ(8) O:O′-bis[(ethanol-κO)copper(II)] |
| title | Tetra-μ-2-methylbenzoato-κ(8)
O:O′-bis[(ethanol-κO)copper(II)] |
| title_full | Tetra-μ-2-methylbenzoato-κ(8)
O:O′-bis[(ethanol-κO)copper(II)] |
| title_fullStr | Tetra-μ-2-methylbenzoato-κ(8)
O:O′-bis[(ethanol-κO)copper(II)] |
| title_full_unstemmed | Tetra-μ-2-methylbenzoato-κ(8)
O:O′-bis[(ethanol-κO)copper(II)] |
| title_short | Tetra-μ-2-methylbenzoato-κ(8)
O:O′-bis[(ethanol-κO)copper(II)] |
| title_sort | tetra-μ-2-methylbenzoato-κ(8)
o:o′-bis[(ethanol-κo)copper(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246983/ https://www.ncbi.nlm.nih.gov/pubmed/22219803 http://dx.doi.org/10.1107/S1600536811042322 |
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