Bis{μ-1,3-bis­[(2-methyl-1H-benzimid­azol-1-yl)meth­yl]benzene-κ(2) N (3):N (3′)}bis­(diiodidocadmium)

In the title compound, [Cd(2)I(4)(C(24)H(22)N(4))(2)], the 1,3-bis­[(2-methyl-1H-benzimidazol-1-yl)meth­yl]benzene ligand bridges two CdI(2) units, forming a centrosymmetric dinuclear complex. The Cd(II) atom adopts a distorted tetra­hedral coordination geometry. In the crystal, complex mol­ecules a...

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Detalles Bibliográficos
Autores principales: Hu, Jiyong, Liu, Junhong, Zhao, Jin’an
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246984/
https://www.ncbi.nlm.nih.gov/pubmed/22219804
http://dx.doi.org/10.1107/S1600536811042334
Descripción
Sumario:In the title compound, [Cd(2)I(4)(C(24)H(22)N(4))(2)], the 1,3-bis­[(2-methyl-1H-benzimidazol-1-yl)meth­yl]benzene ligand bridges two CdI(2) units, forming a centrosymmetric dinuclear complex. The Cd(II) atom adopts a distorted tetra­hedral coordination geometry. In the crystal, complex mol­ecules are linked into columns parallel to [101] by π–π stacking inter­actions, with centroid–centroid distances of 3.558 (2) Å.

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