Bis{μ-1,3-bis­[(2-methyl-1H-benzimid­azol-1-yl)meth­yl]benzene-κ(2) N (3):N (3′)}bis­(diiodidocadmium)

In the title compound, [Cd(2)I(4)(C(24)H(22)N(4))(2)], the 1,3-bis­[(2-methyl-1H-benzimidazol-1-yl)meth­yl]benzene ligand bridges two CdI(2) units, forming a centrosymmetric dinuclear complex. The Cd(II) atom adopts a distorted tetra­hedral coordination geometry. In the crystal, complex mol­ecules a...

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Detalles Bibliográficos
Autores principales: Hu, Jiyong, Liu, Junhong, Zhao, Jin’an
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246984/
https://www.ncbi.nlm.nih.gov/pubmed/22219804
http://dx.doi.org/10.1107/S1600536811042334
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author Hu, Jiyong
Liu, Junhong
Zhao, Jin’an
author_facet Hu, Jiyong
Liu, Junhong
Zhao, Jin’an
author_sort Hu, Jiyong
collection PubMed
description In the title compound, [Cd(2)I(4)(C(24)H(22)N(4))(2)], the 1,3-bis­[(2-methyl-1H-benzimidazol-1-yl)meth­yl]benzene ligand bridges two CdI(2) units, forming a centrosymmetric dinuclear complex. The Cd(II) atom adopts a distorted tetra­hedral coordination geometry. In the crystal, complex mol­ecules are linked into columns parallel to [101] by π–π stacking inter­actions, with centroid–centroid distances of 3.558 (2) Å.
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spelling pubmed-32469842012-01-04 Bis{μ-1,3-bis­[(2-methyl-1H-benzimid­azol-1-yl)meth­yl]benzene-κ(2) N (3):N (3′)}bis­(diiodidocadmium) Hu, Jiyong Liu, Junhong Zhao, Jin’an Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(2)I(4)(C(24)H(22)N(4))(2)], the 1,3-bis­[(2-methyl-1H-benzimidazol-1-yl)meth­yl]benzene ligand bridges two CdI(2) units, forming a centrosymmetric dinuclear complex. The Cd(II) atom adopts a distorted tetra­hedral coordination geometry. In the crystal, complex mol­ecules are linked into columns parallel to [101] by π–π stacking inter­actions, with centroid–centroid distances of 3.558 (2) Å. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246984/ /pubmed/22219804 http://dx.doi.org/10.1107/S1600536811042334 Text en © Hu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hu, Jiyong
Liu, Junhong
Zhao, Jin’an
Bis{μ-1,3-bis­[(2-methyl-1H-benzimid­azol-1-yl)meth­yl]benzene-κ(2) N (3):N (3′)}bis­(diiodidocadmium)
title Bis{μ-1,3-bis­[(2-methyl-1H-benzimid­azol-1-yl)meth­yl]benzene-κ(2) N (3):N (3′)}bis­(diiodidocadmium)
title_full Bis{μ-1,3-bis­[(2-methyl-1H-benzimid­azol-1-yl)meth­yl]benzene-κ(2) N (3):N (3′)}bis­(diiodidocadmium)
title_fullStr Bis{μ-1,3-bis­[(2-methyl-1H-benzimid­azol-1-yl)meth­yl]benzene-κ(2) N (3):N (3′)}bis­(diiodidocadmium)
title_full_unstemmed Bis{μ-1,3-bis­[(2-methyl-1H-benzimid­azol-1-yl)meth­yl]benzene-κ(2) N (3):N (3′)}bis­(diiodidocadmium)
title_short Bis{μ-1,3-bis­[(2-methyl-1H-benzimid­azol-1-yl)meth­yl]benzene-κ(2) N (3):N (3′)}bis­(diiodidocadmium)
title_sort bis{μ-1,3-bis­[(2-methyl-1h-benzimid­azol-1-yl)meth­yl]benzene-κ(2) n (3):n (3′)}bis­(diiodidocadmium)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246984/
https://www.ncbi.nlm.nih.gov/pubmed/22219804
http://dx.doi.org/10.1107/S1600536811042334
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