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1-(3,4-Dichlorobenzyl)pyridinium bis(2-sulfanylidene-1,3-dithiole-4,5-dithiolato-κ(2) S,S′)nickelate(III)
The title compound, (C(12)H(10)Cl(2)N)[Ni(C(3)S(5))(2)], is an ion-pair complex consisting of 1-(3,4-dichlorobenzyl)pyridinium cations and [Ni(dmit)(2)] anions (dmit = 2-sulfanylidene-1,3-dithiole-4,5-dithiolate). In the anion, the Ni(III) ion exhibits a square-planar coordination involving four...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246987/ https://www.ncbi.nlm.nih.gov/pubmed/22219807 http://dx.doi.org/10.1107/S160053681104267X |
Sumario: | The title compound, (C(12)H(10)Cl(2)N)[Ni(C(3)S(5))(2)], is an ion-pair complex consisting of 1-(3,4-dichlorobenzyl)pyridinium cations and [Ni(dmit)(2)] anions (dmit = 2-sulfanylidene-1,3-dithiole-4,5-dithiolate). In the anion, the Ni(III) ion exhibits a square-planar coordination involving four S atoms from two dmit ligands. In the crystal, weak S⋯S [3.368 (2) and 3.482 (3) Å], Ni⋯S [3.680 (2) Å] and Cl⋯S [3.491 (2) Å] interactions and C—H⋯S hydrogen bonds lead to a three-dimensional supramolecular network. |
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