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1-(3,4-Dichloro­benz­yl)pyridinium bis­(2-sulfanyl­idene-1,3-dithiole-4,5-dithiol­ato-κ(2) S,S′)nickelate(III)

The title compound, (C(12)H(10)Cl(2)N)[Ni(C(3)S(5))(2)], is an ion-pair complex consisting of 1-(3,4-dichloro­benz­yl)pyridinium cations and [Ni(dmit)(2)] anions (dmit = 2-sulfanyl­idene-1,3-dithiole-4,5-dithiol­ate). In the anion, the Ni(III) ion exhibits a square-planar coordination involving four...

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Detalles Bibliográficos
Autor principal: Liu, Guang-Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246987/
https://www.ncbi.nlm.nih.gov/pubmed/22219807
http://dx.doi.org/10.1107/S160053681104267X
Descripción
Sumario:The title compound, (C(12)H(10)Cl(2)N)[Ni(C(3)S(5))(2)], is an ion-pair complex consisting of 1-(3,4-dichloro­benz­yl)pyridinium cations and [Ni(dmit)(2)] anions (dmit = 2-sulfanyl­idene-1,3-dithiole-4,5-dithiol­ate). In the anion, the Ni(III) ion exhibits a square-planar coordination involving four S atoms from two dmit ligands. In the crystal, weak S⋯S [3.368 (2) and 3.482 (3) Å], Ni⋯S [3.680 (2) Å] and Cl⋯S [3.491 (2) Å] inter­actions and C—H⋯S hydrogen bonds lead to a three-dimensional supra­molecular network.