1-(3,4-Dichloro­benz­yl)pyridinium bis­(2-sulfanyl­idene-1,3-dithiole-4,5-dithiol­ato-κ(2) S,S′)nickelate(III)

The title compound, (C(12)H(10)Cl(2)N)[Ni(C(3)S(5))(2)], is an ion-pair complex consisting of 1-(3,4-dichloro­benz­yl)pyridinium cations and [Ni(dmit)(2)] anions (dmit = 2-sulfanyl­idene-1,3-dithiole-4,5-dithiol­ate). In the anion, the Ni(III) ion exhibits a square-planar coordination involving four...

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Autor principal: Liu, Guang-Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246987/
https://www.ncbi.nlm.nih.gov/pubmed/22219807
http://dx.doi.org/10.1107/S160053681104267X
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author Liu, Guang-Xiang
author_facet Liu, Guang-Xiang
author_sort Liu, Guang-Xiang
collection PubMed
description The title compound, (C(12)H(10)Cl(2)N)[Ni(C(3)S(5))(2)], is an ion-pair complex consisting of 1-(3,4-dichloro­benz­yl)pyridinium cations and [Ni(dmit)(2)] anions (dmit = 2-sulfanyl­idene-1,3-dithiole-4,5-dithiol­ate). In the anion, the Ni(III) ion exhibits a square-planar coordination involving four S atoms from two dmit ligands. In the crystal, weak S⋯S [3.368 (2) and 3.482 (3) Å], Ni⋯S [3.680 (2) Å] and Cl⋯S [3.491 (2) Å] inter­actions and C—H⋯S hydrogen bonds lead to a three-dimensional supra­molecular network.
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spelling pubmed-32469872012-01-04 1-(3,4-Dichloro­benz­yl)pyridinium bis­(2-sulfanyl­idene-1,3-dithiole-4,5-dithiol­ato-κ(2) S,S′)nickelate(III) Liu, Guang-Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(12)H(10)Cl(2)N)[Ni(C(3)S(5))(2)], is an ion-pair complex consisting of 1-(3,4-dichloro­benz­yl)pyridinium cations and [Ni(dmit)(2)] anions (dmit = 2-sulfanyl­idene-1,3-dithiole-4,5-dithiol­ate). In the anion, the Ni(III) ion exhibits a square-planar coordination involving four S atoms from two dmit ligands. In the crystal, weak S⋯S [3.368 (2) and 3.482 (3) Å], Ni⋯S [3.680 (2) Å] and Cl⋯S [3.491 (2) Å] inter­actions and C—H⋯S hydrogen bonds lead to a three-dimensional supra­molecular network. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246987/ /pubmed/22219807 http://dx.doi.org/10.1107/S160053681104267X Text en © Guang-Xiang Liu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Guang-Xiang
1-(3,4-Dichloro­benz­yl)pyridinium bis­(2-sulfanyl­idene-1,3-dithiole-4,5-dithiol­ato-κ(2) S,S′)nickelate(III)
title 1-(3,4-Dichloro­benz­yl)pyridinium bis­(2-sulfanyl­idene-1,3-dithiole-4,5-dithiol­ato-κ(2) S,S′)nickelate(III)
title_full 1-(3,4-Dichloro­benz­yl)pyridinium bis­(2-sulfanyl­idene-1,3-dithiole-4,5-dithiol­ato-κ(2) S,S′)nickelate(III)
title_fullStr 1-(3,4-Dichloro­benz­yl)pyridinium bis­(2-sulfanyl­idene-1,3-dithiole-4,5-dithiol­ato-κ(2) S,S′)nickelate(III)
title_full_unstemmed 1-(3,4-Dichloro­benz­yl)pyridinium bis­(2-sulfanyl­idene-1,3-dithiole-4,5-dithiol­ato-κ(2) S,S′)nickelate(III)
title_short 1-(3,4-Dichloro­benz­yl)pyridinium bis­(2-sulfanyl­idene-1,3-dithiole-4,5-dithiol­ato-κ(2) S,S′)nickelate(III)
title_sort 1-(3,4-dichloro­benz­yl)pyridinium bis­(2-sulfanyl­idene-1,3-dithiole-4,5-dithiol­ato-κ(2) s,s′)nickelate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246987/
https://www.ncbi.nlm.nih.gov/pubmed/22219807
http://dx.doi.org/10.1107/S160053681104267X
work_keys_str_mv AT liuguangxiang 134dichlorobenzylpyridiniumbis2sulfanylidene13dithiole45dithiolatok2ssnickelateiii

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