[N,N-Bis(diphenyl­phosphan­yl)benzyl­amine-κ(2) P,P′]dichloridonickel(II) dichloro­methane monosolvate

In the title solvated complex, [NiCl(2)(C(31)H(27)NP(2))]·CH(2)Cl(2), the Ni(2+) ion is coordinated by two chloride ions and two P atoms of the chelating N,N-bis­(diphenyl­phosphan­yl)benzyl ligand to generate a strongly distorted cis-NiCl(2)P(2) square-planar geometry for the metal ion. In the crys...

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Detalles Bibliográficos
Autores principales: Yin, Bang-Shao, Li, Tian-Bao, Yang, Ming-Sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246988/
https://www.ncbi.nlm.nih.gov/pubmed/22219808
http://dx.doi.org/10.1107/S1600536811042759
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author Yin, Bang-Shao
Li, Tian-Bao
Yang, Ming-Sheng
author_facet Yin, Bang-Shao
Li, Tian-Bao
Yang, Ming-Sheng
author_sort Yin, Bang-Shao
collection PubMed
description In the title solvated complex, [NiCl(2)(C(31)H(27)NP(2))]·CH(2)Cl(2), the Ni(2+) ion is coordinated by two chloride ions and two P atoms of the chelating N,N-bis­(diphenyl­phosphan­yl)benzyl ligand to generate a strongly distorted cis-NiCl(2)P(2) square-planar geometry for the metal ion. In the crystal, the components are linked by C—H⋯Cl inter­actions.
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spelling pubmed-32469882012-01-04 [N,N-Bis(diphenyl­phosphan­yl)benzyl­amine-κ(2) P,P′]dichloridonickel(II) dichloro­methane monosolvate Yin, Bang-Shao Li, Tian-Bao Yang, Ming-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title solvated complex, [NiCl(2)(C(31)H(27)NP(2))]·CH(2)Cl(2), the Ni(2+) ion is coordinated by two chloride ions and two P atoms of the chelating N,N-bis­(diphenyl­phosphan­yl)benzyl ligand to generate a strongly distorted cis-NiCl(2)P(2) square-planar geometry for the metal ion. In the crystal, the components are linked by C—H⋯Cl inter­actions. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246988/ /pubmed/22219808 http://dx.doi.org/10.1107/S1600536811042759 Text en © Yin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yin, Bang-Shao
Li, Tian-Bao
Yang, Ming-Sheng
[N,N-Bis(diphenyl­phosphan­yl)benzyl­amine-κ(2) P,P′]dichloridonickel(II) dichloro­methane monosolvate
title [N,N-Bis(diphenyl­phosphan­yl)benzyl­amine-κ(2) P,P′]dichloridonickel(II) dichloro­methane monosolvate
title_full [N,N-Bis(diphenyl­phosphan­yl)benzyl­amine-κ(2) P,P′]dichloridonickel(II) dichloro­methane monosolvate
title_fullStr [N,N-Bis(diphenyl­phosphan­yl)benzyl­amine-κ(2) P,P′]dichloridonickel(II) dichloro­methane monosolvate
title_full_unstemmed [N,N-Bis(diphenyl­phosphan­yl)benzyl­amine-κ(2) P,P′]dichloridonickel(II) dichloro­methane monosolvate
title_short [N,N-Bis(diphenyl­phosphan­yl)benzyl­amine-κ(2) P,P′]dichloridonickel(II) dichloro­methane monosolvate
title_sort [n,n-bis(diphenyl­phosphan­yl)benzyl­amine-κ(2) p,p′]dichloridonickel(ii) dichloro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246988/
https://www.ncbi.nlm.nih.gov/pubmed/22219808
http://dx.doi.org/10.1107/S1600536811042759
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AT litianbao nnbisdiphenylphosphanylbenzylaminek2ppdichloridonickeliidichloromethanemonosolvate
AT yangmingsheng nnbisdiphenylphosphanylbenzylaminek2ppdichloridonickeliidichloromethanemonosolvate

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