[N,N-Bis(diphenyl­phosphan­yl)propanamine-κ(2) P,P′]dichloridonickel(II)

In the title complex, [NiCl(2)(C(27)H(27)NP(2))], the Ni(2+) ion is coordinated by two chloride ions and two P atoms of the bidentate N,N-bis­(diphenyl­phosphan­yl)propyl ligand to generate a strongly distorted cis-NiCl(2)P(2) square-planar geometry for the metal ion. A NiP(2)N rhombus occurs within...

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Detalles Bibliográficos
Autores principales: Yin, Bang-Shao, Li, Tian-Bao, Yang, Ming-Sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246989/
https://www.ncbi.nlm.nih.gov/pubmed/22219809
http://dx.doi.org/10.1107/S1600536811042760
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author Yin, Bang-Shao
Li, Tian-Bao
Yang, Ming-Sheng
author_facet Yin, Bang-Shao
Li, Tian-Bao
Yang, Ming-Sheng
author_sort Yin, Bang-Shao
collection PubMed
description In the title complex, [NiCl(2)(C(27)H(27)NP(2))], the Ni(2+) ion is coordinated by two chloride ions and two P atoms of the bidentate N,N-bis­(diphenyl­phosphan­yl)propyl ligand to generate a strongly distorted cis-NiCl(2)P(2) square-planar geometry for the metal ion. A NiP(2)N rhombus occurs within the chelating ligand.
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spelling pubmed-32469892012-01-04 [N,N-Bis(diphenyl­phosphan­yl)propanamine-κ(2) P,P′]dichloridonickel(II) Yin, Bang-Shao Li, Tian-Bao Yang, Ming-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [NiCl(2)(C(27)H(27)NP(2))], the Ni(2+) ion is coordinated by two chloride ions and two P atoms of the bidentate N,N-bis­(diphenyl­phosphan­yl)propyl ligand to generate a strongly distorted cis-NiCl(2)P(2) square-planar geometry for the metal ion. A NiP(2)N rhombus occurs within the chelating ligand. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246989/ /pubmed/22219809 http://dx.doi.org/10.1107/S1600536811042760 Text en © Yin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yin, Bang-Shao
Li, Tian-Bao
Yang, Ming-Sheng
[N,N-Bis(diphenyl­phosphan­yl)propanamine-κ(2) P,P′]dichloridonickel(II)
title [N,N-Bis(diphenyl­phosphan­yl)propanamine-κ(2) P,P′]dichloridonickel(II)
title_full [N,N-Bis(diphenyl­phosphan­yl)propanamine-κ(2) P,P′]dichloridonickel(II)
title_fullStr [N,N-Bis(diphenyl­phosphan­yl)propanamine-κ(2) P,P′]dichloridonickel(II)
title_full_unstemmed [N,N-Bis(diphenyl­phosphan­yl)propanamine-κ(2) P,P′]dichloridonickel(II)
title_short [N,N-Bis(diphenyl­phosphan­yl)propanamine-κ(2) P,P′]dichloridonickel(II)
title_sort [n,n-bis(diphenyl­phosphan­yl)propanamine-κ(2) p,p′]dichloridonickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246989/
https://www.ncbi.nlm.nih.gov/pubmed/22219809
http://dx.doi.org/10.1107/S1600536811042760
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AT yangmingsheng nnbisdiphenylphosphanylpropanaminek2ppdichloridonickelii

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