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[1-tert-Butyl-3-(pyridin-2-ylmethyl-κN)imidazol-2-yl­idene-κC (1)]carbonyl­dichlorido(dimethyl sulfoxide-κS)ruthenium(II)

In the title complex, [RuCl(2)(C(13)H(17)N(3))(C(2)H(6)OS)(CO)], the coordination environment around the Ru atom is slightly distorted octa­hedral. The Cl atoms are mutually trans to the dimethyl sulfoxide ligand and the imidazole carbene C atom, respectively. The carbonyl ligand is located trans to...

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Detalles Bibliográficos
Autores principales: Cheng, Yong, Hua, Wen-Qian, Zhou, Ying-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246990/
https://www.ncbi.nlm.nih.gov/pubmed/22219810
http://dx.doi.org/10.1107/S1600536811042590
Descripción
Sumario:In the title complex, [RuCl(2)(C(13)H(17)N(3))(C(2)H(6)OS)(CO)], the coordination environment around the Ru atom is slightly distorted octa­hedral. The Cl atoms are mutually trans to the dimethyl sulfoxide ligand and the imidazole carbene C atom, respectively. The carbonyl ligand is located trans to the pyridine N atom.