[1-tert-Butyl-3-(pyridin-2-ylmethyl-κN)imidazol-2-yl­idene-κC (1)]carbonyl­dichlorido(dimethyl sulfoxide-κS)ruthenium(II)

In the title complex, [RuCl(2)(C(13)H(17)N(3))(C(2)H(6)OS)(CO)], the coordination environment around the Ru atom is slightly distorted octa­hedral. The Cl atoms are mutually trans to the dimethyl sulfoxide ligand and the imidazole carbene C atom, respectively. The carbonyl ligand is located trans to...

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Detalles Bibliográficos
Autores principales: Cheng, Yong, Hua, Wen-Qian, Zhou, Ying-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246990/
https://www.ncbi.nlm.nih.gov/pubmed/22219810
http://dx.doi.org/10.1107/S1600536811042590
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author Cheng, Yong
Hua, Wen-Qian
Zhou, Ying-Hua
author_facet Cheng, Yong
Hua, Wen-Qian
Zhou, Ying-Hua
author_sort Cheng, Yong
collection PubMed
description In the title complex, [RuCl(2)(C(13)H(17)N(3))(C(2)H(6)OS)(CO)], the coordination environment around the Ru atom is slightly distorted octa­hedral. The Cl atoms are mutually trans to the dimethyl sulfoxide ligand and the imidazole carbene C atom, respectively. The carbonyl ligand is located trans to the pyridine N atom.
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spelling pubmed-32469902012-01-04 [1-tert-Butyl-3-(pyridin-2-ylmethyl-κN)imidazol-2-yl­idene-κC (1)]carbonyl­dichlorido(dimethyl sulfoxide-κS)ruthenium(II) Cheng, Yong Hua, Wen-Qian Zhou, Ying-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [RuCl(2)(C(13)H(17)N(3))(C(2)H(6)OS)(CO)], the coordination environment around the Ru atom is slightly distorted octa­hedral. The Cl atoms are mutually trans to the dimethyl sulfoxide ligand and the imidazole carbene C atom, respectively. The carbonyl ligand is located trans to the pyridine N atom. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246990/ /pubmed/22219810 http://dx.doi.org/10.1107/S1600536811042590 Text en © Cheng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cheng, Yong
Hua, Wen-Qian
Zhou, Ying-Hua
[1-tert-Butyl-3-(pyridin-2-ylmethyl-κN)imidazol-2-yl­idene-κC (1)]carbonyl­dichlorido(dimethyl sulfoxide-κS)ruthenium(II)
title [1-tert-Butyl-3-(pyridin-2-ylmethyl-κN)imidazol-2-yl­idene-κC (1)]carbonyl­dichlorido(dimethyl sulfoxide-κS)ruthenium(II)
title_full [1-tert-Butyl-3-(pyridin-2-ylmethyl-κN)imidazol-2-yl­idene-κC (1)]carbonyl­dichlorido(dimethyl sulfoxide-κS)ruthenium(II)
title_fullStr [1-tert-Butyl-3-(pyridin-2-ylmethyl-κN)imidazol-2-yl­idene-κC (1)]carbonyl­dichlorido(dimethyl sulfoxide-κS)ruthenium(II)
title_full_unstemmed [1-tert-Butyl-3-(pyridin-2-ylmethyl-κN)imidazol-2-yl­idene-κC (1)]carbonyl­dichlorido(dimethyl sulfoxide-κS)ruthenium(II)
title_short [1-tert-Butyl-3-(pyridin-2-ylmethyl-κN)imidazol-2-yl­idene-κC (1)]carbonyl­dichlorido(dimethyl sulfoxide-κS)ruthenium(II)
title_sort [1-tert-butyl-3-(pyridin-2-ylmethyl-κn)imidazol-2-yl­idene-κc (1)]carbonyl­dichlorido(dimethyl sulfoxide-κs)ruthenium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246990/
https://www.ncbi.nlm.nih.gov/pubmed/22219810
http://dx.doi.org/10.1107/S1600536811042590
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