Bis(μ-diethyl­phosphido-κ(2) P:P)bis­[bis(2,4,6-trimethyl­phen­yl)indium(III)]

The title compound, [In(2)(C(9)H(11))(4)(C(4)H(10)P)(2)], contains a centrosymmetric In(2)P(2) core with short inter­molecular In—P bonds. This core has acute P—In—P and obtuse In—P—In bond angles compared with other [R (2)InPR′(2)](2) analogues, due to the presence of the bulky aromatic substituent...

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Detalles Bibliográficos
Autores principales: Briand, Glen G., Decken, Andreas, Knackstedt, Dane A., Martin, Caleb D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246993/
https://www.ncbi.nlm.nih.gov/pubmed/22219813
http://dx.doi.org/10.1107/S1600536811042668
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author Briand, Glen G.
Decken, Andreas
Knackstedt, Dane A.
Martin, Caleb D.
author_facet Briand, Glen G.
Decken, Andreas
Knackstedt, Dane A.
Martin, Caleb D.
author_sort Briand, Glen G.
collection PubMed
description The title compound, [In(2)(C(9)H(11))(4)(C(4)H(10)P)(2)], contains a centrosymmetric In(2)P(2) core with short inter­molecular In—P bonds. This core has acute P—In—P and obtuse In—P—In bond angles compared with other [R (2)InPR′(2)](2) analogues, due to the presence of the bulky aromatic substituents on the In atom and the non-sterically demanding ethyl substituents on the P atom.
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spelling pubmed-32469932012-01-04 Bis(μ-diethyl­phosphido-κ(2) P:P)bis­[bis(2,4,6-trimethyl­phen­yl)indium(III)] Briand, Glen G. Decken, Andreas Knackstedt, Dane A. Martin, Caleb D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [In(2)(C(9)H(11))(4)(C(4)H(10)P)(2)], contains a centrosymmetric In(2)P(2) core with short inter­molecular In—P bonds. This core has acute P—In—P and obtuse In—P—In bond angles compared with other [R (2)InPR′(2)](2) analogues, due to the presence of the bulky aromatic substituents on the In atom and the non-sterically demanding ethyl substituents on the P atom. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246993/ /pubmed/22219813 http://dx.doi.org/10.1107/S1600536811042668 Text en © Briand et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Briand, Glen G.
Decken, Andreas
Knackstedt, Dane A.
Martin, Caleb D.
Bis(μ-diethyl­phosphido-κ(2) P:P)bis­[bis(2,4,6-trimethyl­phen­yl)indium(III)]
title Bis(μ-diethyl­phosphido-κ(2) P:P)bis­[bis(2,4,6-trimethyl­phen­yl)indium(III)]
title_full Bis(μ-diethyl­phosphido-κ(2) P:P)bis­[bis(2,4,6-trimethyl­phen­yl)indium(III)]
title_fullStr Bis(μ-diethyl­phosphido-κ(2) P:P)bis­[bis(2,4,6-trimethyl­phen­yl)indium(III)]
title_full_unstemmed Bis(μ-diethyl­phosphido-κ(2) P:P)bis­[bis(2,4,6-trimethyl­phen­yl)indium(III)]
title_short Bis(μ-diethyl­phosphido-κ(2) P:P)bis­[bis(2,4,6-trimethyl­phen­yl)indium(III)]
title_sort bis(μ-diethyl­phosphido-κ(2) p:p)bis­[bis(2,4,6-trimethyl­phen­yl)indium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246993/
https://www.ncbi.nlm.nih.gov/pubmed/22219813
http://dx.doi.org/10.1107/S1600536811042668
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