[(4E,11E)-5,7,12,14-Tetra­benzyl-7,14-dimethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene]copper(II) bis(per­chlorate)

The complete cation in the title compound, [Cu(C(40)H(48)N(4))](ClO(4))(2), is generated by the operation of a crystallographic centre of inversion. The Cu(II) ion exists in a tetra­gonally distorted trans-N(4)O(2) coordination geometry defined by the four N atoms of the macrocyclic ligand and two w...

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Detalles Bibliográficos
Autores principales: Roy, Tapashi G., Hazari, Saroj K. S., Nath, Babul C., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246995/
https://www.ncbi.nlm.nih.gov/pubmed/22219815
http://dx.doi.org/10.1107/S1600536811042796
Descripción
Sumario:The complete cation in the title compound, [Cu(C(40)H(48)N(4))](ClO(4))(2), is generated by the operation of a crystallographic centre of inversion. The Cu(II) ion exists in a tetra­gonally distorted trans-N(4)O(2) coordination geometry defined by the four N atoms of the macrocyclic ligand and two weakly bound perchlorate-O atoms from two anions. The N—H atoms form intra­molecular N—H⋯O(perchlorate) hydrogen bonds. Disorder was resolved in the –CH(2)–NH– portion of the macrocycle with the major component having a site-occupancy factor of 0.570 (6).

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