[(4E,11E)-5,7,12,14-Tetra­benzyl-7,14-dimethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene]copper(II) bis(per­chlorate)

The complete cation in the title compound, [Cu(C(40)H(48)N(4))](ClO(4))(2), is generated by the operation of a crystallographic centre of inversion. The Cu(II) ion exists in a tetra­gonally distorted trans-N(4)O(2) coordination geometry defined by the four N atoms of the macrocyclic ligand and two w...

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Autores principales: Roy, Tapashi G., Hazari, Saroj K. S., Nath, Babul C., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246995/
https://www.ncbi.nlm.nih.gov/pubmed/22219815
http://dx.doi.org/10.1107/S1600536811042796
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author Roy, Tapashi G.
Hazari, Saroj K. S.
Nath, Babul C.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Roy, Tapashi G.
Hazari, Saroj K. S.
Nath, Babul C.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Roy, Tapashi G.
collection PubMed
description The complete cation in the title compound, [Cu(C(40)H(48)N(4))](ClO(4))(2), is generated by the operation of a crystallographic centre of inversion. The Cu(II) ion exists in a tetra­gonally distorted trans-N(4)O(2) coordination geometry defined by the four N atoms of the macrocyclic ligand and two weakly bound perchlorate-O atoms from two anions. The N—H atoms form intra­molecular N—H⋯O(perchlorate) hydrogen bonds. Disorder was resolved in the –CH(2)–NH– portion of the macrocycle with the major component having a site-occupancy factor of 0.570 (6).
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spelling pubmed-32469952012-01-04 [(4E,11E)-5,7,12,14-Tetra­benzyl-7,14-dimethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene]copper(II) bis(per­chlorate) Roy, Tapashi G. Hazari, Saroj K. S. Nath, Babul C. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete cation in the title compound, [Cu(C(40)H(48)N(4))](ClO(4))(2), is generated by the operation of a crystallographic centre of inversion. The Cu(II) ion exists in a tetra­gonally distorted trans-N(4)O(2) coordination geometry defined by the four N atoms of the macrocyclic ligand and two weakly bound perchlorate-O atoms from two anions. The N—H atoms form intra­molecular N—H⋯O(perchlorate) hydrogen bonds. Disorder was resolved in the –CH(2)–NH– portion of the macrocycle with the major component having a site-occupancy factor of 0.570 (6). International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246995/ /pubmed/22219815 http://dx.doi.org/10.1107/S1600536811042796 Text en © Roy et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Roy, Tapashi G.
Hazari, Saroj K. S.
Nath, Babul C.
Ng, Seik Weng
Tiekink, Edward R. T.
[(4E,11E)-5,7,12,14-Tetra­benzyl-7,14-dimethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene]copper(II) bis(per­chlorate)
title [(4E,11E)-5,7,12,14-Tetra­benzyl-7,14-dimethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene]copper(II) bis(per­chlorate)
title_full [(4E,11E)-5,7,12,14-Tetra­benzyl-7,14-dimethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene]copper(II) bis(per­chlorate)
title_fullStr [(4E,11E)-5,7,12,14-Tetra­benzyl-7,14-dimethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene]copper(II) bis(per­chlorate)
title_full_unstemmed [(4E,11E)-5,7,12,14-Tetra­benzyl-7,14-dimethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene]copper(II) bis(per­chlorate)
title_short [(4E,11E)-5,7,12,14-Tetra­benzyl-7,14-dimethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene]copper(II) bis(per­chlorate)
title_sort [(4e,11e)-5,7,12,14-tetra­benzyl-7,14-dimethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene]copper(ii) bis(per­chlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246995/
https://www.ncbi.nlm.nih.gov/pubmed/22219815
http://dx.doi.org/10.1107/S1600536811042796
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