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catena-Poly[[lead(II)-μ-(2-oxidobenz­aldehyde isonicotinoylhydrazonato)] methanol monosolvate]

The Pb atom in the polymeric title compound, {[Pb(C(13)H(9)N(3)O(2))]·CH(3)OH}(n), is five-coordinated within an N(2)O(2) donor set and a lone pair of electrons, as the N-isonicotinamido­salicylaldiminate ligand coordinates the Pb(II) atom via the O,N,O′-donors and simultaneously bridges a neighbour...

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Detalles Bibliográficos
Autores principales: Shahverdizadeh, Gholam Hossein, Ng, Seik Weng, Tiekink, Edward R. T., Mirtamizdoust, Babak
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246996/
https://www.ncbi.nlm.nih.gov/pubmed/22219816
http://dx.doi.org/10.1107/S1600536811043078
Descripción
Sumario:The Pb atom in the polymeric title compound, {[Pb(C(13)H(9)N(3)O(2))]·CH(3)OH}(n), is five-coordinated within an N(2)O(2) donor set and a lone pair of electrons, as the N-isonicotinamido­salicylaldiminate ligand coordinates the Pb(II) atom via the O,N,O′-donors and simultaneously bridges a neighbouring Pb atom via the pyridine N atom; the coordination geometry is based on a trigonal bipyramid with the O atoms in axial positions. The resulting supra­molecular chain is a 3(1) helix along the c axis. These chains are linked via inter­molecular Pb⋯O,N inter­actions, as well as O—H⋯O hydrogen bonds.