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catena-Poly[[lead(II)-μ-(2-oxidobenzaldehyde isonicotinoylhydrazonato)] methanol monosolvate]
The Pb atom in the polymeric title compound, {[Pb(C(13)H(9)N(3)O(2))]·CH(3)OH}(n), is five-coordinated within an N(2)O(2) donor set and a lone pair of electrons, as the N-isonicotinamidosalicylaldiminate ligand coordinates the Pb(II) atom via the O,N,O′-donors and simultaneously bridges a neighbour...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246996/ https://www.ncbi.nlm.nih.gov/pubmed/22219816 http://dx.doi.org/10.1107/S1600536811043078 |
Sumario: | The Pb atom in the polymeric title compound, {[Pb(C(13)H(9)N(3)O(2))]·CH(3)OH}(n), is five-coordinated within an N(2)O(2) donor set and a lone pair of electrons, as the N-isonicotinamidosalicylaldiminate ligand coordinates the Pb(II) atom via the O,N,O′-donors and simultaneously bridges a neighbouring Pb atom via the pyridine N atom; the coordination geometry is based on a trigonal bipyramid with the O atoms in axial positions. The resulting supramolecular chain is a 3(1) helix along the c axis. These chains are linked via intermolecular Pb⋯O,N interactions, as well as O—H⋯O hydrogen bonds. |
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