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catena-Poly[2-methyl-1H-imidazol-3-ium [(aqua­chloridocadmate)-di-μ-chlorido]]

The asymmetric unit of the title compound, {(C(4)H(7)N(2))[CdCl(3)(H(2)O)]}(n), contains one 1-methyl-1H-imidazol-3-ium cation, one Cd(II) atom, three Cl atoms and one water mol­ecule. Adjacent Cd ions are inter­connected alternately by paired Cl(−) bridges to generate an infinite one-dimensional co...

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Detalles Bibliográficos
Autor principal: Zhu, Run-Qiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246997/
https://www.ncbi.nlm.nih.gov/pubmed/22219817
http://dx.doi.org/10.1107/S1600536811042905
Descripción
Sumario:The asymmetric unit of the title compound, {(C(4)H(7)N(2))[CdCl(3)(H(2)O)]}(n), contains one 1-methyl-1H-imidazol-3-ium cation, one Cd(II) atom, three Cl atoms and one water mol­ecule. Adjacent Cd ions are inter­connected alternately by paired Cl(−) bridges to generate an infinite one-dimensional coordination chain along the b axis. In the chain, the crystallographically unique Cd(II) atom, with a distorted octa­hedral geometry, is coordinated by five Cl(−) ions and one water mol­ecule. Intra-chain O—H⋯Cl hydrogen bonding and N—H⋯Cl hydrogen bonding between the cations and the anionic chains consolidate the crystal packing.