catena-Poly[2-methyl-1H-imidazol-3-ium [(aqua­chloridocadmate)-di-μ-chlorido]]

The asymmetric unit of the title compound, {(C(4)H(7)N(2))[CdCl(3)(H(2)O)]}(n), contains one 1-methyl-1H-imidazol-3-ium cation, one Cd(II) atom, three Cl atoms and one water mol­ecule. Adjacent Cd ions are inter­connected alternately by paired Cl(−) bridges to generate an infinite one-dimensional co...

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Detalles Bibliográficos
Autor principal: Zhu, Run-Qiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246997/
https://www.ncbi.nlm.nih.gov/pubmed/22219817
http://dx.doi.org/10.1107/S1600536811042905
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author Zhu, Run-Qiang
author_facet Zhu, Run-Qiang
author_sort Zhu, Run-Qiang
collection PubMed
description The asymmetric unit of the title compound, {(C(4)H(7)N(2))[CdCl(3)(H(2)O)]}(n), contains one 1-methyl-1H-imidazol-3-ium cation, one Cd(II) atom, three Cl atoms and one water mol­ecule. Adjacent Cd ions are inter­connected alternately by paired Cl(−) bridges to generate an infinite one-dimensional coordination chain along the b axis. In the chain, the crystallographically unique Cd(II) atom, with a distorted octa­hedral geometry, is coordinated by five Cl(−) ions and one water mol­ecule. Intra-chain O—H⋯Cl hydrogen bonding and N—H⋯Cl hydrogen bonding between the cations and the anionic chains consolidate the crystal packing.
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spelling pubmed-32469972012-01-04 catena-Poly[2-methyl-1H-imidazol-3-ium [(aqua­chloridocadmate)-di-μ-chlorido]] Zhu, Run-Qiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {(C(4)H(7)N(2))[CdCl(3)(H(2)O)]}(n), contains one 1-methyl-1H-imidazol-3-ium cation, one Cd(II) atom, three Cl atoms and one water mol­ecule. Adjacent Cd ions are inter­connected alternately by paired Cl(−) bridges to generate an infinite one-dimensional coordination chain along the b axis. In the chain, the crystallographically unique Cd(II) atom, with a distorted octa­hedral geometry, is coordinated by five Cl(−) ions and one water mol­ecule. Intra-chain O—H⋯Cl hydrogen bonding and N—H⋯Cl hydrogen bonding between the cations and the anionic chains consolidate the crystal packing. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246997/ /pubmed/22219817 http://dx.doi.org/10.1107/S1600536811042905 Text en © Run-Qiang Zhu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Run-Qiang
catena-Poly[2-methyl-1H-imidazol-3-ium [(aqua­chloridocadmate)-di-μ-chlorido]]
title catena-Poly[2-methyl-1H-imidazol-3-ium [(aqua­chloridocadmate)-di-μ-chlorido]]
title_full catena-Poly[2-methyl-1H-imidazol-3-ium [(aqua­chloridocadmate)-di-μ-chlorido]]
title_fullStr catena-Poly[2-methyl-1H-imidazol-3-ium [(aqua­chloridocadmate)-di-μ-chlorido]]
title_full_unstemmed catena-Poly[2-methyl-1H-imidazol-3-ium [(aqua­chloridocadmate)-di-μ-chlorido]]
title_short catena-Poly[2-methyl-1H-imidazol-3-ium [(aqua­chloridocadmate)-di-μ-chlorido]]
title_sort catena-poly[2-methyl-1h-imidazol-3-ium [(aqua­chloridocadmate)-di-μ-chlorido]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246997/
https://www.ncbi.nlm.nih.gov/pubmed/22219817
http://dx.doi.org/10.1107/S1600536811042905
work_keys_str_mv AT zhurunqiang catenapoly2methyl1himidazol3iumaquachloridocadmatedimchlorido

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