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catena-Poly[[bis(1-ethyl-1H-imidazole-κN (3))copper(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)]
The title compound, [Cu(C(2)O(4))(C(5)H(8)N(2))(2)](n), is composed of one-dimensional linear chains running parallel to the a axis. In the chain, trans-[Cu(imidazole)(2)](2+) units are sequentially bridged by bis-bidentate oxalate ligands, resulting in an octahedral CuO(4)N(2) donor set. The Cu⋯Cu...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246998/ https://www.ncbi.nlm.nih.gov/pubmed/22219818 http://dx.doi.org/10.1107/S1600536811043121 |
Sumario: | The title compound, [Cu(C(2)O(4))(C(5)H(8)N(2))(2)](n), is composed of one-dimensional linear chains running parallel to the a axis. In the chain, trans-[Cu(imidazole)(2)](2+) units are sequentially bridged by bis-bidentate oxalate ligands, resulting in an octahedral CuO(4)N(2) donor set. The Cu⋯Cu separation through the oxalate bridge is 5.620 (5) Å. Both the Cu atoms and the C—C bond of the oxalate bridge are bisected by inversion centres. |
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