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catena-Poly[[bis(1-ethyl-1H-imidazole-κN (3))copper(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)]
The title compound, [Cu(C(2)O(4))(C(5)H(8)N(2))(2)](n), is composed of one-dimensional linear chains running parallel to the a axis. In the chain, trans-[Cu(imidazole)(2)](2+) units are sequentially bridged by bis-bidentate oxalate ligands, resulting in an octahedral CuO(4)N(2) donor set. The Cu⋯Cu...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246998/ https://www.ncbi.nlm.nih.gov/pubmed/22219818 http://dx.doi.org/10.1107/S1600536811043121 |
| _version_ | 1782220022382329856 |
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| author | Xu, Qian |
| author_facet | Xu, Qian |
| author_sort | Xu, Qian |
| collection | PubMed |
| description | The title compound, [Cu(C(2)O(4))(C(5)H(8)N(2))(2)](n), is composed of one-dimensional linear chains running parallel to the a axis. In the chain, trans-[Cu(imidazole)(2)](2+) units are sequentially bridged by bis-bidentate oxalate ligands, resulting in an octahedral CuO(4)N(2) donor set. The Cu⋯Cu separation through the oxalate bridge is 5.620 (5) Å. Both the Cu atoms and the C—C bond of the oxalate bridge are bisected by inversion centres. |
| format | Online Article Text |
| id | pubmed-3246998 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32469982012-01-04 catena-Poly[[bis(1-ethyl-1H-imidazole-κN (3))copper(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)] Xu, Qian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(2)O(4))(C(5)H(8)N(2))(2)](n), is composed of one-dimensional linear chains running parallel to the a axis. In the chain, trans-[Cu(imidazole)(2)](2+) units are sequentially bridged by bis-bidentate oxalate ligands, resulting in an octahedral CuO(4)N(2) donor set. The Cu⋯Cu separation through the oxalate bridge is 5.620 (5) Å. Both the Cu atoms and the C—C bond of the oxalate bridge are bisected by inversion centres. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246998/ /pubmed/22219818 http://dx.doi.org/10.1107/S1600536811043121 Text en © Qian Xu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Xu, Qian catena-Poly[[bis(1-ethyl-1H-imidazole-κN (3))copper(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)] |
| title |
catena-Poly[[bis(1-ethyl-1H-imidazole-κN
(3))copper(II)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
| title_full |
catena-Poly[[bis(1-ethyl-1H-imidazole-κN
(3))copper(II)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
| title_fullStr |
catena-Poly[[bis(1-ethyl-1H-imidazole-κN
(3))copper(II)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
| title_full_unstemmed |
catena-Poly[[bis(1-ethyl-1H-imidazole-κN
(3))copper(II)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
| title_short |
catena-Poly[[bis(1-ethyl-1H-imidazole-κN
(3))copper(II)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
| title_sort | catena-poly[[bis(1-ethyl-1h-imidazole-κn
(3))copper(ii)]-μ-oxalato-κ(4)
o
(1),o
(2):o
(1′),o
(2′)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246998/ https://www.ncbi.nlm.nih.gov/pubmed/22219818 http://dx.doi.org/10.1107/S1600536811043121 |
| work_keys_str_mv | AT xuqian catenapolybis1ethyl1himidazolekn3copperiimoxalatok4o1o2o1o2 |