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Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis(μ(2)-2-phenoxypropionato-κ(2) O:O′)cobalt(II)]
In the polymeric title compound, [Co(C(9)H(9)O(3))(2)(C(10)H(8)N(2))](n), the Co(II) ion is located on a twofold rotation axis and is six-coordinated by two N atoms from two 4,4′-bipyridine (4,4′-bipy) ligands in axial positions and by four O atoms from four 2-phenoxypropionate (POPA) anions in eq...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247000/ https://www.ncbi.nlm.nih.gov/pubmed/22219820 http://dx.doi.org/10.1107/S1600536811042875 |
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author | Shen, Jin-Bei Liu, Jia-Lu Zhao, Guo-Liang |
author_facet | Shen, Jin-Bei Liu, Jia-Lu Zhao, Guo-Liang |
author_sort | Shen, Jin-Bei |
collection | PubMed |
description | In the polymeric title compound, [Co(C(9)H(9)O(3))(2)(C(10)H(8)N(2))](n), the Co(II) ion is located on a twofold rotation axis and is six-coordinated by two N atoms from two 4,4′-bipyridine (4,4′-bipy) ligands in axial positions and by four O atoms from four 2-phenoxypropionate (POPA) anions in equatorial positions, defining a slightly distorted octahedral geometry. The carboxylate group of the POPA anion displays a bis-monodentate mode, linking pairs of Co(II) ions into a chain parallel to [001]. Adjacent chains are connected in a perpendicular manner through 4,4′-bipy ligands into layers parallel to (100). The 4,4′-bipy ligand is likewise located on a twofold rotation axis, with a dihedral angle between the two pyridine rings of 57.05 (7)°. C—H⋯O hydrogen-bonding interactions are present within the layers. π–π stacking interactions between the POPA benzene rings of neighbouring layers [centroid-to-centroid distance = 3.976 (3) Å and plane-to-plane distance = 3.618 (3) Å] stabilize the packing of the structure. |
format | Online Article Text |
id | pubmed-3247000 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32470002012-01-04 Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis(μ(2)-2-phenoxypropionato-κ(2) O:O′)cobalt(II)] Shen, Jin-Bei Liu, Jia-Lu Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title compound, [Co(C(9)H(9)O(3))(2)(C(10)H(8)N(2))](n), the Co(II) ion is located on a twofold rotation axis and is six-coordinated by two N atoms from two 4,4′-bipyridine (4,4′-bipy) ligands in axial positions and by four O atoms from four 2-phenoxypropionate (POPA) anions in equatorial positions, defining a slightly distorted octahedral geometry. The carboxylate group of the POPA anion displays a bis-monodentate mode, linking pairs of Co(II) ions into a chain parallel to [001]. Adjacent chains are connected in a perpendicular manner through 4,4′-bipy ligands into layers parallel to (100). The 4,4′-bipy ligand is likewise located on a twofold rotation axis, with a dihedral angle between the two pyridine rings of 57.05 (7)°. C—H⋯O hydrogen-bonding interactions are present within the layers. π–π stacking interactions between the POPA benzene rings of neighbouring layers [centroid-to-centroid distance = 3.976 (3) Å and plane-to-plane distance = 3.618 (3) Å] stabilize the packing of the structure. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3247000/ /pubmed/22219820 http://dx.doi.org/10.1107/S1600536811042875 Text en © Shen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shen, Jin-Bei Liu, Jia-Lu Zhao, Guo-Liang Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis(μ(2)-2-phenoxypropionato-κ(2) O:O′)cobalt(II)] |
title | Poly[(μ(2)-4,4′-bipyridine-κ(2)
N:N′)bis(μ(2)-2-phenoxypropionato-κ(2)
O:O′)cobalt(II)] |
title_full | Poly[(μ(2)-4,4′-bipyridine-κ(2)
N:N′)bis(μ(2)-2-phenoxypropionato-κ(2)
O:O′)cobalt(II)] |
title_fullStr | Poly[(μ(2)-4,4′-bipyridine-κ(2)
N:N′)bis(μ(2)-2-phenoxypropionato-κ(2)
O:O′)cobalt(II)] |
title_full_unstemmed | Poly[(μ(2)-4,4′-bipyridine-κ(2)
N:N′)bis(μ(2)-2-phenoxypropionato-κ(2)
O:O′)cobalt(II)] |
title_short | Poly[(μ(2)-4,4′-bipyridine-κ(2)
N:N′)bis(μ(2)-2-phenoxypropionato-κ(2)
O:O′)cobalt(II)] |
title_sort | poly[(μ(2)-4,4′-bipyridine-κ(2)
n:n′)bis(μ(2)-2-phenoxypropionato-κ(2)
o:o′)cobalt(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247000/ https://www.ncbi.nlm.nih.gov/pubmed/22219820 http://dx.doi.org/10.1107/S1600536811042875 |
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