Cargando…

Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis­(μ(2)-2-phen­oxy­propionato-κ(2) O:O′)cobalt(II)]

In the polymeric title compound, [Co(C(9)H(9)O(3))(2)(C(10)H(8)N(2))](n), the Co(II) ion is located on a twofold rotation axis and is six-coordinated by two N atoms from two 4,4′-bipyridine (4,4′-bipy) ligands in axial positions and by four O atoms from four 2-phen­oxy­propionate (POPA) anions in eq...

Descripción completa

Detalles Bibliográficos
Autores principales: Shen, Jin-Bei, Liu, Jia-Lu, Zhao, Guo-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247000/
https://www.ncbi.nlm.nih.gov/pubmed/22219820
http://dx.doi.org/10.1107/S1600536811042875
_version_ 1782220022824828928
author Shen, Jin-Bei
Liu, Jia-Lu
Zhao, Guo-Liang
author_facet Shen, Jin-Bei
Liu, Jia-Lu
Zhao, Guo-Liang
author_sort Shen, Jin-Bei
collection PubMed
description In the polymeric title compound, [Co(C(9)H(9)O(3))(2)(C(10)H(8)N(2))](n), the Co(II) ion is located on a twofold rotation axis and is six-coordinated by two N atoms from two 4,4′-bipyridine (4,4′-bipy) ligands in axial positions and by four O atoms from four 2-phen­oxy­propionate (POPA) anions in equatorial positions, defining a slightly distorted octa­hedral geometry. The carboxyl­ate group of the POPA anion displays a bis-monodentate mode, linking pairs of Co(II) ions into a chain parallel to [001]. Adjacent chains are connected in a perpendicular manner through 4,4′-bipy ligands into layers parallel to (100). The 4,4′-bipy ligand is likewise located on a twofold rotation axis, with a dihedral angle between the two pyridine rings of 57.05 (7)°. C—H⋯O hydrogen-bonding inter­actions are present within the layers. π–π stacking inter­actions between the POPA benzene rings of neighbouring layers [centroid-to-centroid distance = 3.976 (3) Å and plane-to-plane distance = 3.618 (3) Å] stabilize the packing of the structure.
format Online
Article
Text
id pubmed-3247000
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32470002012-01-04 Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis­(μ(2)-2-phen­oxy­propionato-κ(2) O:O′)cobalt(II)] Shen, Jin-Bei Liu, Jia-Lu Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title compound, [Co(C(9)H(9)O(3))(2)(C(10)H(8)N(2))](n), the Co(II) ion is located on a twofold rotation axis and is six-coordinated by two N atoms from two 4,4′-bipyridine (4,4′-bipy) ligands in axial positions and by four O atoms from four 2-phen­oxy­propionate (POPA) anions in equatorial positions, defining a slightly distorted octa­hedral geometry. The carboxyl­ate group of the POPA anion displays a bis-monodentate mode, linking pairs of Co(II) ions into a chain parallel to [001]. Adjacent chains are connected in a perpendicular manner through 4,4′-bipy ligands into layers parallel to (100). The 4,4′-bipy ligand is likewise located on a twofold rotation axis, with a dihedral angle between the two pyridine rings of 57.05 (7)°. C—H⋯O hydrogen-bonding inter­actions are present within the layers. π–π stacking inter­actions between the POPA benzene rings of neighbouring layers [centroid-to-centroid distance = 3.976 (3) Å and plane-to-plane distance = 3.618 (3) Å] stabilize the packing of the structure. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3247000/ /pubmed/22219820 http://dx.doi.org/10.1107/S1600536811042875 Text en © Shen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shen, Jin-Bei
Liu, Jia-Lu
Zhao, Guo-Liang
Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis­(μ(2)-2-phen­oxy­propionato-κ(2) O:O′)cobalt(II)]
title Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis­(μ(2)-2-phen­oxy­propionato-κ(2) O:O′)cobalt(II)]
title_full Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis­(μ(2)-2-phen­oxy­propionato-κ(2) O:O′)cobalt(II)]
title_fullStr Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis­(μ(2)-2-phen­oxy­propionato-κ(2) O:O′)cobalt(II)]
title_full_unstemmed Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis­(μ(2)-2-phen­oxy­propionato-κ(2) O:O′)cobalt(II)]
title_short Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis­(μ(2)-2-phen­oxy­propionato-κ(2) O:O′)cobalt(II)]
title_sort poly[(μ(2)-4,4′-bipyridine-κ(2) n:n′)bis­(μ(2)-2-phen­oxy­propionato-κ(2) o:o′)cobalt(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247000/
https://www.ncbi.nlm.nih.gov/pubmed/22219820
http://dx.doi.org/10.1107/S1600536811042875
work_keys_str_mv AT shenjinbei polym244bipyridinek2nnbism22phenoxypropionatok2oocobaltii
AT liujialu polym244bipyridinek2nnbism22phenoxypropionatok2oocobaltii
AT zhaoguoliang polym244bipyridinek2nnbism22phenoxypropionatok2oocobaltii