Cargando…

Poly[tetra­aquadi-μ(4)-oxalato-lutetium(III)potassium]

In the title compound, [KLu(C(2)O(4))(2)(H(2)O)(4)](n), the Lu(III) ion lies on a site of [Image: see text] symmetry in a dodeca­hedron defined by eight O atoms from four oxalate ligands. The K atom lies on another site of the same symmetry and is coordinated by four oxalate O atoms and four O water...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Feng-Ming, Sun, Tao-Zhu, Hou, Guang-Feng, Yan, Peng-Fei, Li, Guang-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247002/
https://www.ncbi.nlm.nih.gov/pubmed/22219822
http://dx.doi.org/10.1107/S1600536811042061
Descripción
Sumario:In the title compound, [KLu(C(2)O(4))(2)(H(2)O)(4)](n), the Lu(III) ion lies on a site of [Image: see text] symmetry in a dodeca­hedron defined by eight O atoms from four oxalate ligands. The K atom lies on another site of the same symmetry and is coordinated by four oxalate O atoms and four O water atoms. The mid-point of the C—C bond of the oxalate group lies on an inversion center. In the packing structure, each oxalate ligand links two Lu(III) and two K atoms, forming a three-dimensional open framework with channels running along [001]. Inter­molecular O—H⋯O hydrogen bonds occur.