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Poly[tetraaquadi-μ(4)-oxalato-lutetium(III)potassium]
In the title compound, [KLu(C(2)O(4))(2)(H(2)O)(4)](n), the Lu(III) ion lies on a site of [Image: see text] symmetry in a dodecahedron defined by eight O atoms from four oxalate ligands. The K atom lies on another site of the same symmetry and is coordinated by four oxalate O atoms and four O water...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247002/ https://www.ncbi.nlm.nih.gov/pubmed/22219822 http://dx.doi.org/10.1107/S1600536811042061 |
Sumario: | In the title compound, [KLu(C(2)O(4))(2)(H(2)O)(4)](n), the Lu(III) ion lies on a site of [Image: see text] symmetry in a dodecahedron defined by eight O atoms from four oxalate ligands. The K atom lies on another site of the same symmetry and is coordinated by four oxalate O atoms and four O water atoms. The mid-point of the C—C bond of the oxalate group lies on an inversion center. In the packing structure, each oxalate ligand links two Lu(III) and two K atoms, forming a three-dimensional open framework with channels running along [001]. Intermolecular O—H⋯O hydrogen bonds occur. |
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