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Poly[tetra­aquadi-μ(4)-oxalato-lutetium(III)potassium]

In the title compound, [KLu(C(2)O(4))(2)(H(2)O)(4)](n), the Lu(III) ion lies on a site of [Image: see text] symmetry in a dodeca­hedron defined by eight O atoms from four oxalate ligands. The K atom lies on another site of the same symmetry and is coordinated by four oxalate O atoms and four O water...

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Autores principales: Zhang, Feng-Ming, Sun, Tao-Zhu, Hou, Guang-Feng, Yan, Peng-Fei, Li, Guang-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247002/
https://www.ncbi.nlm.nih.gov/pubmed/22219822
http://dx.doi.org/10.1107/S1600536811042061
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author Zhang, Feng-Ming
Sun, Tao-Zhu
Hou, Guang-Feng
Yan, Peng-Fei
Li, Guang-Ming
author_facet Zhang, Feng-Ming
Sun, Tao-Zhu
Hou, Guang-Feng
Yan, Peng-Fei
Li, Guang-Ming
author_sort Zhang, Feng-Ming
collection PubMed
description In the title compound, [KLu(C(2)O(4))(2)(H(2)O)(4)](n), the Lu(III) ion lies on a site of [Image: see text] symmetry in a dodeca­hedron defined by eight O atoms from four oxalate ligands. The K atom lies on another site of the same symmetry and is coordinated by four oxalate O atoms and four O water atoms. The mid-point of the C—C bond of the oxalate group lies on an inversion center. In the packing structure, each oxalate ligand links two Lu(III) and two K atoms, forming a three-dimensional open framework with channels running along [001]. Inter­molecular O—H⋯O hydrogen bonds occur.
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spelling pubmed-32470022012-01-04 Poly[tetra­aquadi-μ(4)-oxalato-lutetium(III)potassium] Zhang, Feng-Ming Sun, Tao-Zhu Hou, Guang-Feng Yan, Peng-Fei Li, Guang-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [KLu(C(2)O(4))(2)(H(2)O)(4)](n), the Lu(III) ion lies on a site of [Image: see text] symmetry in a dodeca­hedron defined by eight O atoms from four oxalate ligands. The K atom lies on another site of the same symmetry and is coordinated by four oxalate O atoms and four O water atoms. The mid-point of the C—C bond of the oxalate group lies on an inversion center. In the packing structure, each oxalate ligand links two Lu(III) and two K atoms, forming a three-dimensional open framework with channels running along [001]. Inter­molecular O—H⋯O hydrogen bonds occur. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3247002/ /pubmed/22219822 http://dx.doi.org/10.1107/S1600536811042061 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Feng-Ming
Sun, Tao-Zhu
Hou, Guang-Feng
Yan, Peng-Fei
Li, Guang-Ming
Poly[tetra­aquadi-μ(4)-oxalato-lutetium(III)potassium]
title Poly[tetra­aquadi-μ(4)-oxalato-lutetium(III)potassium]
title_full Poly[tetra­aquadi-μ(4)-oxalato-lutetium(III)potassium]
title_fullStr Poly[tetra­aquadi-μ(4)-oxalato-lutetium(III)potassium]
title_full_unstemmed Poly[tetra­aquadi-μ(4)-oxalato-lutetium(III)potassium]
title_short Poly[tetra­aquadi-μ(4)-oxalato-lutetium(III)potassium]
title_sort poly[tetra­aquadi-μ(4)-oxalato-lutetium(iii)potassium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247002/
https://www.ncbi.nlm.nih.gov/pubmed/22219822
http://dx.doi.org/10.1107/S1600536811042061
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