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Poly[tetraaquadi-μ(4)-oxalato-lutetium(III)potassium]
In the title compound, [KLu(C(2)O(4))(2)(H(2)O)(4)](n), the Lu(III) ion lies on a site of [Image: see text] symmetry in a dodecahedron defined by eight O atoms from four oxalate ligands. The K atom lies on another site of the same symmetry and is coordinated by four oxalate O atoms and four O water...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247002/ https://www.ncbi.nlm.nih.gov/pubmed/22219822 http://dx.doi.org/10.1107/S1600536811042061 |
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author | Zhang, Feng-Ming Sun, Tao-Zhu Hou, Guang-Feng Yan, Peng-Fei Li, Guang-Ming |
author_facet | Zhang, Feng-Ming Sun, Tao-Zhu Hou, Guang-Feng Yan, Peng-Fei Li, Guang-Ming |
author_sort | Zhang, Feng-Ming |
collection | PubMed |
description | In the title compound, [KLu(C(2)O(4))(2)(H(2)O)(4)](n), the Lu(III) ion lies on a site of [Image: see text] symmetry in a dodecahedron defined by eight O atoms from four oxalate ligands. The K atom lies on another site of the same symmetry and is coordinated by four oxalate O atoms and four O water atoms. The mid-point of the C—C bond of the oxalate group lies on an inversion center. In the packing structure, each oxalate ligand links two Lu(III) and two K atoms, forming a three-dimensional open framework with channels running along [001]. Intermolecular O—H⋯O hydrogen bonds occur. |
format | Online Article Text |
id | pubmed-3247002 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32470022012-01-04 Poly[tetraaquadi-μ(4)-oxalato-lutetium(III)potassium] Zhang, Feng-Ming Sun, Tao-Zhu Hou, Guang-Feng Yan, Peng-Fei Li, Guang-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [KLu(C(2)O(4))(2)(H(2)O)(4)](n), the Lu(III) ion lies on a site of [Image: see text] symmetry in a dodecahedron defined by eight O atoms from four oxalate ligands. The K atom lies on another site of the same symmetry and is coordinated by four oxalate O atoms and four O water atoms. The mid-point of the C—C bond of the oxalate group lies on an inversion center. In the packing structure, each oxalate ligand links two Lu(III) and two K atoms, forming a three-dimensional open framework with channels running along [001]. Intermolecular O—H⋯O hydrogen bonds occur. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3247002/ /pubmed/22219822 http://dx.doi.org/10.1107/S1600536811042061 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Feng-Ming Sun, Tao-Zhu Hou, Guang-Feng Yan, Peng-Fei Li, Guang-Ming Poly[tetraaquadi-μ(4)-oxalato-lutetium(III)potassium] |
title | Poly[tetraaquadi-μ(4)-oxalato-lutetium(III)potassium] |
title_full | Poly[tetraaquadi-μ(4)-oxalato-lutetium(III)potassium] |
title_fullStr | Poly[tetraaquadi-μ(4)-oxalato-lutetium(III)potassium] |
title_full_unstemmed | Poly[tetraaquadi-μ(4)-oxalato-lutetium(III)potassium] |
title_short | Poly[tetraaquadi-μ(4)-oxalato-lutetium(III)potassium] |
title_sort | poly[tetraaquadi-μ(4)-oxalato-lutetium(iii)potassium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247002/ https://www.ncbi.nlm.nih.gov/pubmed/22219822 http://dx.doi.org/10.1107/S1600536811042061 |
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