Dichlorido(furfuryl­amine-κN)(η(6)-hexa­methyl­benzene)­ruthenium(II)

The single-crystal X-ray structure analysis of [RuCl(2)(C(12)H(18))(C(5)H(7)NO)] reveals a distorted piano-stool geometry around the Ru(II) atom, with a hexa­methyl­benzene ligand, two chloride ligands and a furfuryl­amine ligand, the latter coordinating through the amine group. In the crystal, a di...

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Detalles Bibliográficos
Autores principales: Garci, Amine, Thai, Trieu-Tien, Süss-Fink, Georg, Therrien, Bruno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247003/
https://www.ncbi.nlm.nih.gov/pubmed/22219823
http://dx.doi.org/10.1107/S1600536811043170
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author Garci, Amine
Thai, Trieu-Tien
Süss-Fink, Georg
Therrien, Bruno
author_facet Garci, Amine
Thai, Trieu-Tien
Süss-Fink, Georg
Therrien, Bruno
author_sort Garci, Amine
collection PubMed
description The single-crystal X-ray structure analysis of [RuCl(2)(C(12)H(18))(C(5)H(7)NO)] reveals a distorted piano-stool geometry around the Ru(II) atom, with a hexa­methyl­benzene ligand, two chloride ligands and a furfuryl­amine ligand, the latter coordinating through the amine group. In the crystal, a dimeric structure is observed as a result of N—H⋯Cl inter­actions between two symmetry-related mol­ecules.
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spelling pubmed-32470032012-01-04 Dichlorido(furfuryl­amine-κN)(η(6)-hexa­methyl­benzene)­ruthenium(II) Garci, Amine Thai, Trieu-Tien Süss-Fink, Georg Therrien, Bruno Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The single-crystal X-ray structure analysis of [RuCl(2)(C(12)H(18))(C(5)H(7)NO)] reveals a distorted piano-stool geometry around the Ru(II) atom, with a hexa­methyl­benzene ligand, two chloride ligands and a furfuryl­amine ligand, the latter coordinating through the amine group. In the crystal, a dimeric structure is observed as a result of N—H⋯Cl inter­actions between two symmetry-related mol­ecules. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3247003/ /pubmed/22219823 http://dx.doi.org/10.1107/S1600536811043170 Text en © Garci et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Garci, Amine
Thai, Trieu-Tien
Süss-Fink, Georg
Therrien, Bruno
Dichlorido(furfuryl­amine-κN)(η(6)-hexa­methyl­benzene)­ruthenium(II)
title Dichlorido(furfuryl­amine-κN)(η(6)-hexa­methyl­benzene)­ruthenium(II)
title_full Dichlorido(furfuryl­amine-κN)(η(6)-hexa­methyl­benzene)­ruthenium(II)
title_fullStr Dichlorido(furfuryl­amine-κN)(η(6)-hexa­methyl­benzene)­ruthenium(II)
title_full_unstemmed Dichlorido(furfuryl­amine-κN)(η(6)-hexa­methyl­benzene)­ruthenium(II)
title_short Dichlorido(furfuryl­amine-κN)(η(6)-hexa­methyl­benzene)­ruthenium(II)
title_sort dichlorido(furfuryl­amine-κn)(η(6)-hexa­methyl­benzene)­ruthenium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247003/
https://www.ncbi.nlm.nih.gov/pubmed/22219823
http://dx.doi.org/10.1107/S1600536811043170
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AT therrienbruno dichloridofurfurylamineknē6hexamethylbenzenerutheniumii

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