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Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)(μ(2)-2,2-dimeth­yl­cyclo­pentane-1,3-dicarboxyl­ato-κ(4) O (1),O (1′):O (3),O (3′))cadmium]

In the title polymeric compound, [Cd(C(9)H(12)O(4))(C(10)H(8)N(2))](n), the Cd(II) atom is located on a twofold rotation axis and is coordinated by two 4,4′-bipyridine ligands and two 2,2-dimethyl­cyclo­pentane-1,3-dicarboxyl­ate ions. The carboxyl­ate ion and the N-heterocycle both function as brid...

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Detalles Bibliográficos
Autores principales: Zhang, Xian-Fa, Gao, Shan, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247004/
https://www.ncbi.nlm.nih.gov/pubmed/22219824
http://dx.doi.org/10.1107/S1600536811042656
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author Zhang, Xian-Fa
Gao, Shan
Ng, Seik Weng
author_facet Zhang, Xian-Fa
Gao, Shan
Ng, Seik Weng
author_sort Zhang, Xian-Fa
collection PubMed
description In the title polymeric compound, [Cd(C(9)H(12)O(4))(C(10)H(8)N(2))](n), the Cd(II) atom is located on a twofold rotation axis and is coordinated by two 4,4′-bipyridine ligands and two 2,2-dimethyl­cyclo­pentane-1,3-dicarboxyl­ate ions. The carboxyl­ate ion and the N-heterocycle both function as bridges to link adjacent Cd(II) atoms to result in the formation of a layer structure parallel to (010). The mid-point of the central C—C bond of the 4,4′-bipyridine ligand is located on an inversion center. In the crystal, the carboxyl­ate ion is disordered over a twofold rotation axis in respect of its methyl group and the cyclo­pentane ring.
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spelling pubmed-32470042012-01-04 Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)(μ(2)-2,2-dimeth­yl­cyclo­pentane-1,3-dicarboxyl­ato-κ(4) O (1),O (1′):O (3),O (3′))cadmium] Zhang, Xian-Fa Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymeric compound, [Cd(C(9)H(12)O(4))(C(10)H(8)N(2))](n), the Cd(II) atom is located on a twofold rotation axis and is coordinated by two 4,4′-bipyridine ligands and two 2,2-dimethyl­cyclo­pentane-1,3-dicarboxyl­ate ions. The carboxyl­ate ion and the N-heterocycle both function as bridges to link adjacent Cd(II) atoms to result in the formation of a layer structure parallel to (010). The mid-point of the central C—C bond of the 4,4′-bipyridine ligand is located on an inversion center. In the crystal, the carboxyl­ate ion is disordered over a twofold rotation axis in respect of its methyl group and the cyclo­pentane ring. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3247004/ /pubmed/22219824 http://dx.doi.org/10.1107/S1600536811042656 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Xian-Fa
Gao, Shan
Ng, Seik Weng
Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)(μ(2)-2,2-dimeth­yl­cyclo­pentane-1,3-dicarboxyl­ato-κ(4) O (1),O (1′):O (3),O (3′))cadmium]
title Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)(μ(2)-2,2-dimeth­yl­cyclo­pentane-1,3-dicarboxyl­ato-κ(4) O (1),O (1′):O (3),O (3′))cadmium]
title_full Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)(μ(2)-2,2-dimeth­yl­cyclo­pentane-1,3-dicarboxyl­ato-κ(4) O (1),O (1′):O (3),O (3′))cadmium]
title_fullStr Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)(μ(2)-2,2-dimeth­yl­cyclo­pentane-1,3-dicarboxyl­ato-κ(4) O (1),O (1′):O (3),O (3′))cadmium]
title_full_unstemmed Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)(μ(2)-2,2-dimeth­yl­cyclo­pentane-1,3-dicarboxyl­ato-κ(4) O (1),O (1′):O (3),O (3′))cadmium]
title_short Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)(μ(2)-2,2-dimeth­yl­cyclo­pentane-1,3-dicarboxyl­ato-κ(4) O (1),O (1′):O (3),O (3′))cadmium]
title_sort poly[(μ(2)-4,4′-bipyridine-κ(2) n:n′)(μ(2)-2,2-dimeth­yl­cyclo­pentane-1,3-dicarboxyl­ato-κ(4) o (1),o (1′):o (3),o (3′))cadmium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247004/
https://www.ncbi.nlm.nih.gov/pubmed/22219824
http://dx.doi.org/10.1107/S1600536811042656
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