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Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)(μ(2)-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ(4) O (1),O (1′):O (3),O (3′))cadmium]
In the title polymeric compound, [Cd(C(9)H(12)O(4))(C(10)H(8)N(2))](n), the Cd(II) atom is located on a twofold rotation axis and is coordinated by two 4,4′-bipyridine ligands and two 2,2-dimethylcyclopentane-1,3-dicarboxylate ions. The carboxylate ion and the N-heterocycle both function as brid...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247004/ https://www.ncbi.nlm.nih.gov/pubmed/22219824 http://dx.doi.org/10.1107/S1600536811042656 |
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author | Zhang, Xian-Fa Gao, Shan Ng, Seik Weng |
author_facet | Zhang, Xian-Fa Gao, Shan Ng, Seik Weng |
author_sort | Zhang, Xian-Fa |
collection | PubMed |
description | In the title polymeric compound, [Cd(C(9)H(12)O(4))(C(10)H(8)N(2))](n), the Cd(II) atom is located on a twofold rotation axis and is coordinated by two 4,4′-bipyridine ligands and two 2,2-dimethylcyclopentane-1,3-dicarboxylate ions. The carboxylate ion and the N-heterocycle both function as bridges to link adjacent Cd(II) atoms to result in the formation of a layer structure parallel to (010). The mid-point of the central C—C bond of the 4,4′-bipyridine ligand is located on an inversion center. In the crystal, the carboxylate ion is disordered over a twofold rotation axis in respect of its methyl group and the cyclopentane ring. |
format | Online Article Text |
id | pubmed-3247004 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32470042012-01-04 Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)(μ(2)-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ(4) O (1),O (1′):O (3),O (3′))cadmium] Zhang, Xian-Fa Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymeric compound, [Cd(C(9)H(12)O(4))(C(10)H(8)N(2))](n), the Cd(II) atom is located on a twofold rotation axis and is coordinated by two 4,4′-bipyridine ligands and two 2,2-dimethylcyclopentane-1,3-dicarboxylate ions. The carboxylate ion and the N-heterocycle both function as bridges to link adjacent Cd(II) atoms to result in the formation of a layer structure parallel to (010). The mid-point of the central C—C bond of the 4,4′-bipyridine ligand is located on an inversion center. In the crystal, the carboxylate ion is disordered over a twofold rotation axis in respect of its methyl group and the cyclopentane ring. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3247004/ /pubmed/22219824 http://dx.doi.org/10.1107/S1600536811042656 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Xian-Fa Gao, Shan Ng, Seik Weng Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)(μ(2)-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ(4) O (1),O (1′):O (3),O (3′))cadmium] |
title | Poly[(μ(2)-4,4′-bipyridine-κ(2)
N:N′)(μ(2)-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ(4)
O
(1),O
(1′):O
(3),O
(3′))cadmium] |
title_full | Poly[(μ(2)-4,4′-bipyridine-κ(2)
N:N′)(μ(2)-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ(4)
O
(1),O
(1′):O
(3),O
(3′))cadmium] |
title_fullStr | Poly[(μ(2)-4,4′-bipyridine-κ(2)
N:N′)(μ(2)-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ(4)
O
(1),O
(1′):O
(3),O
(3′))cadmium] |
title_full_unstemmed | Poly[(μ(2)-4,4′-bipyridine-κ(2)
N:N′)(μ(2)-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ(4)
O
(1),O
(1′):O
(3),O
(3′))cadmium] |
title_short | Poly[(μ(2)-4,4′-bipyridine-κ(2)
N:N′)(μ(2)-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ(4)
O
(1),O
(1′):O
(3),O
(3′))cadmium] |
title_sort | poly[(μ(2)-4,4′-bipyridine-κ(2)
n:n′)(μ(2)-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ(4)
o
(1),o
(1′):o
(3),o
(3′))cadmium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247004/ https://www.ncbi.nlm.nih.gov/pubmed/22219824 http://dx.doi.org/10.1107/S1600536811042656 |
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