N-(3-Chloro­phen­yl)-4-methyl­benzamide hemihydrate

In the title compound, C(14)H(12)ClNO·0.5H(2)O, the water mol­ecule is located on a twofold axis of symmetry. The meta-Cl atom in the aniline ring is positioned anti to the N—H bond. The two benzene rings make a dihedral angle of 40.40 (11)°. The crystal structure is stabilized by inter­molecular N—...

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Detalles Bibliográficos
Autores principales: Rodrigues, Vinola Z., Kucková, Lenka, Gowda, B. Thimme, Kožíšek, Jozef
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247315/
https://www.ncbi.nlm.nih.gov/pubmed/22219933
http://dx.doi.org/10.1107/S1600536811040992
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author Rodrigues, Vinola Z.
Kucková, Lenka
Gowda, B. Thimme
Kožíšek, Jozef
author_facet Rodrigues, Vinola Z.
Kucková, Lenka
Gowda, B. Thimme
Kožíšek, Jozef
author_sort Rodrigues, Vinola Z.
collection PubMed
description In the title compound, C(14)H(12)ClNO·0.5H(2)O, the water mol­ecule is located on a twofold axis of symmetry. The meta-Cl atom in the aniline ring is positioned anti to the N—H bond. The two benzene rings make a dihedral angle of 40.40 (11)°. The crystal structure is stabilized by inter­molecular N—H⋯O and O—H⋯O hydrogen bonds, which link the mol­ecules into chains along the a axis.
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spelling pubmed-32473152012-01-04 N-(3-Chloro­phen­yl)-4-methyl­benzamide hemihydrate Rodrigues, Vinola Z. Kucková, Lenka Gowda, B. Thimme Kožíšek, Jozef Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(12)ClNO·0.5H(2)O, the water mol­ecule is located on a twofold axis of symmetry. The meta-Cl atom in the aniline ring is positioned anti to the N—H bond. The two benzene rings make a dihedral angle of 40.40 (11)°. The crystal structure is stabilized by inter­molecular N—H⋯O and O—H⋯O hydrogen bonds, which link the mol­ecules into chains along the a axis. International Union of Crystallography 2011-10-08 /pmc/articles/PMC3247315/ /pubmed/22219933 http://dx.doi.org/10.1107/S1600536811040992 Text en © Rodrigues et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rodrigues, Vinola Z.
Kucková, Lenka
Gowda, B. Thimme
Kožíšek, Jozef
N-(3-Chloro­phen­yl)-4-methyl­benzamide hemihydrate
title N-(3-Chloro­phen­yl)-4-methyl­benzamide hemihydrate
title_full N-(3-Chloro­phen­yl)-4-methyl­benzamide hemihydrate
title_fullStr N-(3-Chloro­phen­yl)-4-methyl­benzamide hemihydrate
title_full_unstemmed N-(3-Chloro­phen­yl)-4-methyl­benzamide hemihydrate
title_short N-(3-Chloro­phen­yl)-4-methyl­benzamide hemihydrate
title_sort n-(3-chloro­phen­yl)-4-methyl­benzamide hemihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247315/
https://www.ncbi.nlm.nih.gov/pubmed/22219933
http://dx.doi.org/10.1107/S1600536811040992
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