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(E,E)-1,2-Bis[4-(prop-2-yn-1-yloxy)benzylidene]hydrazine
The molecule of the title compound, C(20)H(16)N(2)O(2), is centrosymmetric with the mid-point of the central N—N bond located on an inversion center. The configuration around the C=N bond is E. The whole molecule (except for the H atoms) is approximately planar, with an r.m.s. deviation of 0.07 Å....
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247316/ https://www.ncbi.nlm.nih.gov/pubmed/22219934 http://dx.doi.org/10.1107/S160053681104102X |
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author | Al-Mehana, Wisam Naji Atiyah Yahya, Rosiyah Lo, Kong Mun |
author_facet | Al-Mehana, Wisam Naji Atiyah Yahya, Rosiyah Lo, Kong Mun |
author_sort | Al-Mehana, Wisam Naji Atiyah |
collection | PubMed |
description | The molecule of the title compound, C(20)H(16)N(2)O(2), is centrosymmetric with the mid-point of the central N—N bond located on an inversion center. The configuration around the C=N bond is E. The whole molecule (except for the H atoms) is approximately planar, with an r.m.s. deviation of 0.07 Å. In the crystal, the presence of weak intermolecular C—H⋯O hydrogen bonding involving each acetylene H atom and the adjacent phenoxy O atom results in the formation of supramolecular chains. |
format | Online Article Text |
id | pubmed-3247316 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32473162012-01-04 (E,E)-1,2-Bis[4-(prop-2-yn-1-yloxy)benzylidene]hydrazine Al-Mehana, Wisam Naji Atiyah Yahya, Rosiyah Lo, Kong Mun Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(20)H(16)N(2)O(2), is centrosymmetric with the mid-point of the central N—N bond located on an inversion center. The configuration around the C=N bond is E. The whole molecule (except for the H atoms) is approximately planar, with an r.m.s. deviation of 0.07 Å. In the crystal, the presence of weak intermolecular C—H⋯O hydrogen bonding involving each acetylene H atom and the adjacent phenoxy O atom results in the formation of supramolecular chains. International Union of Crystallography 2011-10-08 /pmc/articles/PMC3247316/ /pubmed/22219934 http://dx.doi.org/10.1107/S160053681104102X Text en © Al-Mehana et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Al-Mehana, Wisam Naji Atiyah Yahya, Rosiyah Lo, Kong Mun (E,E)-1,2-Bis[4-(prop-2-yn-1-yloxy)benzylidene]hydrazine |
title | (E,E)-1,2-Bis[4-(prop-2-yn-1-yloxy)benzylidene]hydrazine |
title_full | (E,E)-1,2-Bis[4-(prop-2-yn-1-yloxy)benzylidene]hydrazine |
title_fullStr | (E,E)-1,2-Bis[4-(prop-2-yn-1-yloxy)benzylidene]hydrazine |
title_full_unstemmed | (E,E)-1,2-Bis[4-(prop-2-yn-1-yloxy)benzylidene]hydrazine |
title_short | (E,E)-1,2-Bis[4-(prop-2-yn-1-yloxy)benzylidene]hydrazine |
title_sort | (e,e)-1,2-bis[4-(prop-2-yn-1-yloxy)benzylidene]hydrazine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247316/ https://www.ncbi.nlm.nih.gov/pubmed/22219934 http://dx.doi.org/10.1107/S160053681104102X |
work_keys_str_mv | AT almehanawisamnajiatiyah ee12bis4prop2yn1yloxybenzylidenehydrazine AT yahyarosiyah ee12bis4prop2yn1yloxybenzylidenehydrazine AT lokongmun ee12bis4prop2yn1yloxybenzylidenehydrazine |