1-(1-Adamantylmeth­yl)-1H-benzimidazole

The asymmetric unit of the title compound, C(18)H(22)N(2), contains two independent mol­ecules which differ slightly with respect to the torsion angles involving the atoms joining the adamantyl and benzimidazole groups. The bond angles in the adamantane cage vary within the range 108.27 (9)–110.55 (...

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Autores principales: Černochová, Jarmila, Nečas, Marek, Kuřitka, Ivo, Vícha, Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247322/
https://www.ncbi.nlm.nih.gov/pubmed/22219940
http://dx.doi.org/10.1107/S1600536811041018
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author Černochová, Jarmila
Nečas, Marek
Kuřitka, Ivo
Vícha, Robert
author_facet Černochová, Jarmila
Nečas, Marek
Kuřitka, Ivo
Vícha, Robert
author_sort Černochová, Jarmila
collection PubMed
description The asymmetric unit of the title compound, C(18)H(22)N(2), contains two independent mol­ecules which differ slightly with respect to the torsion angles involving the atoms joining the adamantyl and benzimidazole groups. The bond angles in the adamantane cage vary within the range 108.27 (9)–110.55 (10)°. The benzimidazole ring system in both mol­ecules is essentially planar, the maximum deviations from the best planes being 0.0134 (15) and 0.0229 (14) Å. In the crystal, weak C—H⋯π inter­actions link the molecules.
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spelling pubmed-32473222012-01-04 1-(1-Adamantylmeth­yl)-1H-benzimidazole Černochová, Jarmila Nečas, Marek Kuřitka, Ivo Vícha, Robert Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(18)H(22)N(2), contains two independent mol­ecules which differ slightly with respect to the torsion angles involving the atoms joining the adamantyl and benzimidazole groups. The bond angles in the adamantane cage vary within the range 108.27 (9)–110.55 (10)°. The benzimidazole ring system in both mol­ecules is essentially planar, the maximum deviations from the best planes being 0.0134 (15) and 0.0229 (14) Å. In the crystal, weak C—H⋯π inter­actions link the molecules. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3247322/ /pubmed/22219940 http://dx.doi.org/10.1107/S1600536811041018 Text en © Černochová et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Černochová, Jarmila
Nečas, Marek
Kuřitka, Ivo
Vícha, Robert
1-(1-Adamantylmeth­yl)-1H-benzimidazole
title 1-(1-Adamantylmeth­yl)-1H-benzimidazole
title_full 1-(1-Adamantylmeth­yl)-1H-benzimidazole
title_fullStr 1-(1-Adamantylmeth­yl)-1H-benzimidazole
title_full_unstemmed 1-(1-Adamantylmeth­yl)-1H-benzimidazole
title_short 1-(1-Adamantylmeth­yl)-1H-benzimidazole
title_sort 1-(1-adamantylmeth­yl)-1h-benzimidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247322/
https://www.ncbi.nlm.nih.gov/pubmed/22219940
http://dx.doi.org/10.1107/S1600536811041018
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