Methyl (E)-3-(2-bromo-4,5-dimeth­oxy­benzyl­idene)dithio­carbazate

The title compound, C(11)H(13)BrN(2)O(2)S(2), was obtained from the condensation reaction of methyl dithio­carbazate and 2-bromo-4,5-dimeth­oxy­benzaldehyde. In the mol­ecule, the benzene ring and dithio­carbazate fragment are located on opposite sides of the C=N bond, showing an E conformation. The...

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Detalles Bibliográficos
Autores principales: Fan, Zheng, Huang, Yan-Lan, Tong, Fang, Huang, Yi-Wei, Shan, Shang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247333/
https://www.ncbi.nlm.nih.gov/pubmed/22219951
http://dx.doi.org/10.1107/S1600536811039304
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author Fan, Zheng
Huang, Yan-Lan
Tong, Fang
Huang, Yi-Wei
Shan, Shang
author_facet Fan, Zheng
Huang, Yan-Lan
Tong, Fang
Huang, Yi-Wei
Shan, Shang
author_sort Fan, Zheng
collection PubMed
description The title compound, C(11)H(13)BrN(2)O(2)S(2), was obtained from the condensation reaction of methyl dithio­carbazate and 2-bromo-4,5-dimeth­oxy­benzaldehyde. In the mol­ecule, the benzene ring and dithio­carbazate fragment are located on opposite sides of the C=N bond, showing an E conformation. The dithio­carbazate fragment is approximately planar (r.m.s deviation = 0.0281 Å) and the mean plane is oriented at a dihedral angle of 11.38 (15)° with respect to the benzene ring. In the crystal, pairs of N—H⋯S hydrogen bonds link the mol­ecules into centrosymmetric dimers.
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spelling pubmed-32473332012-01-04 Methyl (E)-3-(2-bromo-4,5-dimeth­oxy­benzyl­idene)dithio­carbazate Fan, Zheng Huang, Yan-Lan Tong, Fang Huang, Yi-Wei Shan, Shang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(11)H(13)BrN(2)O(2)S(2), was obtained from the condensation reaction of methyl dithio­carbazate and 2-bromo-4,5-dimeth­oxy­benzaldehyde. In the mol­ecule, the benzene ring and dithio­carbazate fragment are located on opposite sides of the C=N bond, showing an E conformation. The dithio­carbazate fragment is approximately planar (r.m.s deviation = 0.0281 Å) and the mean plane is oriented at a dihedral angle of 11.38 (15)° with respect to the benzene ring. In the crystal, pairs of N—H⋯S hydrogen bonds link the mol­ecules into centrosymmetric dimers. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3247333/ /pubmed/22219951 http://dx.doi.org/10.1107/S1600536811039304 Text en © Fan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fan, Zheng
Huang, Yan-Lan
Tong, Fang
Huang, Yi-Wei
Shan, Shang
Methyl (E)-3-(2-bromo-4,5-dimeth­oxy­benzyl­idene)dithio­carbazate
title Methyl (E)-3-(2-bromo-4,5-dimeth­oxy­benzyl­idene)dithio­carbazate
title_full Methyl (E)-3-(2-bromo-4,5-dimeth­oxy­benzyl­idene)dithio­carbazate
title_fullStr Methyl (E)-3-(2-bromo-4,5-dimeth­oxy­benzyl­idene)dithio­carbazate
title_full_unstemmed Methyl (E)-3-(2-bromo-4,5-dimeth­oxy­benzyl­idene)dithio­carbazate
title_short Methyl (E)-3-(2-bromo-4,5-dimeth­oxy­benzyl­idene)dithio­carbazate
title_sort methyl (e)-3-(2-bromo-4,5-dimeth­oxy­benzyl­idene)dithio­carbazate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247333/
https://www.ncbi.nlm.nih.gov/pubmed/22219951
http://dx.doi.org/10.1107/S1600536811039304
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AT huangyiwei methyle32bromo45dimethoxybenzylidenedithiocarbazate
AT shanshang methyle32bromo45dimethoxybenzylidenedithiocarbazate

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