2-(1,3-Benzothia­zol-2-yl)guanidin-2-ium acetate

In the title compound, C(8)H(9)N(4)S(−)·C(2)H(3)O(2) (−), the cation is essentially planar (r.m.s deviation = 0.037 Å) with the guanidine unit bent out of the plane of the fused-ring system by 4.6 (3)°. In the asymmetric unit, the cations and anions are linked into R (2) (2)(8) motifs. In the crysta...

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Autores principales: Horton, Peter N., Coles, Simon J., Mohamed, Shaaban K., El-Remaily, Mahmoud A. A., Soliman, A. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247334/
https://www.ncbi.nlm.nih.gov/pubmed/22219952
http://dx.doi.org/10.1107/S160053681104089X
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author Horton, Peter N.
Coles, Simon J.
Mohamed, Shaaban K.
El-Remaily, Mahmoud A. A.
Soliman, A. M.
author_facet Horton, Peter N.
Coles, Simon J.
Mohamed, Shaaban K.
El-Remaily, Mahmoud A. A.
Soliman, A. M.
author_sort Horton, Peter N.
collection PubMed
description In the title compound, C(8)H(9)N(4)S(−)·C(2)H(3)O(2) (−), the cation is essentially planar (r.m.s deviation = 0.037 Å) with the guanidine unit bent out of the plane of the fused-ring system by 4.6 (3)°. In the asymmetric unit, the cations and anions are linked into R (2) (2)(8) motifs. In the crystal, further N—H⋯O and N—H⋯N hydrogen bonds link the components into a two-dimensional network.
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spelling pubmed-32473342012-01-04 2-(1,3-Benzothia­zol-2-yl)guanidin-2-ium acetate Horton, Peter N. Coles, Simon J. Mohamed, Shaaban K. El-Remaily, Mahmoud A. A. Soliman, A. M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(8)H(9)N(4)S(−)·C(2)H(3)O(2) (−), the cation is essentially planar (r.m.s deviation = 0.037 Å) with the guanidine unit bent out of the plane of the fused-ring system by 4.6 (3)°. In the asymmetric unit, the cations and anions are linked into R (2) (2)(8) motifs. In the crystal, further N—H⋯O and N—H⋯N hydrogen bonds link the components into a two-dimensional network. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3247334/ /pubmed/22219952 http://dx.doi.org/10.1107/S160053681104089X Text en © Horton et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Horton, Peter N.
Coles, Simon J.
Mohamed, Shaaban K.
El-Remaily, Mahmoud A. A.
Soliman, A. M.
2-(1,3-Benzothia­zol-2-yl)guanidin-2-ium acetate
title 2-(1,3-Benzothia­zol-2-yl)guanidin-2-ium acetate
title_full 2-(1,3-Benzothia­zol-2-yl)guanidin-2-ium acetate
title_fullStr 2-(1,3-Benzothia­zol-2-yl)guanidin-2-ium acetate
title_full_unstemmed 2-(1,3-Benzothia­zol-2-yl)guanidin-2-ium acetate
title_short 2-(1,3-Benzothia­zol-2-yl)guanidin-2-ium acetate
title_sort 2-(1,3-benzothia­zol-2-yl)guanidin-2-ium acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247334/
https://www.ncbi.nlm.nih.gov/pubmed/22219952
http://dx.doi.org/10.1107/S160053681104089X
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