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4-Chloro-N-(3,4-dimethylphenyl)-2-methylbenzenesulfonamide
In the title compound, C(15)H(16)ClNO(2)S, the conformation of the N—C bond in the C—SO(2)—NH—C segment is gauche with respect to the S=O bonds. Further, the N—H bond in the C—SO(2)—NH—C segment is syn with respect to the meta-methyl group in the aniline benzene ring and the ortho-methyl group in th...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247343/ https://www.ncbi.nlm.nih.gov/pubmed/22219961 http://dx.doi.org/10.1107/S1600536811041341 |
Sumario: | In the title compound, C(15)H(16)ClNO(2)S, the conformation of the N—C bond in the C—SO(2)—NH—C segment is gauche with respect to the S=O bonds. Further, the N—H bond in the C—SO(2)—NH—C segment is syn with respect to the meta-methyl group in the aniline benzene ring and the ortho-methyl group in the sulfonyl benzene ring. The C—SO(2)—NH—C torsion angle is −49.72 (18)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 71.6 (1)°. The crystal structure features inversion-related dimers linked by pairs of N—H⋯O hydrogen bonds. |
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