N-Benzyl-4-methyl-6-phenyl­pyrimidin-2-amine

In the title compound, C(18)H(17)N(3), the dihedral angles between the central pyrimidine ring and its directly-bonded and N-bonded pendant phenyl rings are 25.48 (6) and 80.33 (6)°, respectively. The dihedral angle between the phenyl rings is 79.66 (6)°. In the crystal, inversion dimers linked by p...

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Autores principales: Fun, Hoong-Kun, Hemamalini, Madhukar, Hazra, Anita, Goswami, Shyamaprosad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247345/
https://www.ncbi.nlm.nih.gov/pubmed/22219963
http://dx.doi.org/10.1107/S1600536811041365
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author Fun, Hoong-Kun
Hemamalini, Madhukar
Hazra, Anita
Goswami, Shyamaprosad
author_facet Fun, Hoong-Kun
Hemamalini, Madhukar
Hazra, Anita
Goswami, Shyamaprosad
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(18)H(17)N(3), the dihedral angles between the central pyrimidine ring and its directly-bonded and N-bonded pendant phenyl rings are 25.48 (6) and 80.33 (6)°, respectively. The dihedral angle between the phenyl rings is 79.66 (6)°. In the crystal, inversion dimers linked by pairs of N—H⋯N hydrogen bonds generate R (2) (2)(8) loops. The crystal structure also features weak π–π [centroid–centroid separation = 3.6720 (7) Å] and C—H⋯π inter­actions.
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spelling pubmed-32473452012-01-04 N-Benzyl-4-methyl-6-phenyl­pyrimidin-2-amine Fun, Hoong-Kun Hemamalini, Madhukar Hazra, Anita Goswami, Shyamaprosad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(17)N(3), the dihedral angles between the central pyrimidine ring and its directly-bonded and N-bonded pendant phenyl rings are 25.48 (6) and 80.33 (6)°, respectively. The dihedral angle between the phenyl rings is 79.66 (6)°. In the crystal, inversion dimers linked by pairs of N—H⋯N hydrogen bonds generate R (2) (2)(8) loops. The crystal structure also features weak π–π [centroid–centroid separation = 3.6720 (7) Å] and C—H⋯π inter­actions. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3247345/ /pubmed/22219963 http://dx.doi.org/10.1107/S1600536811041365 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Hemamalini, Madhukar
Hazra, Anita
Goswami, Shyamaprosad
N-Benzyl-4-methyl-6-phenyl­pyrimidin-2-amine
title N-Benzyl-4-methyl-6-phenyl­pyrimidin-2-amine
title_full N-Benzyl-4-methyl-6-phenyl­pyrimidin-2-amine
title_fullStr N-Benzyl-4-methyl-6-phenyl­pyrimidin-2-amine
title_full_unstemmed N-Benzyl-4-methyl-6-phenyl­pyrimidin-2-amine
title_short N-Benzyl-4-methyl-6-phenyl­pyrimidin-2-amine
title_sort n-benzyl-4-methyl-6-phenyl­pyrimidin-2-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247345/
https://www.ncbi.nlm.nih.gov/pubmed/22219963
http://dx.doi.org/10.1107/S1600536811041365
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AT goswamishyamaprosad nbenzyl4methyl6phenylpyrimidin2amine

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