4-Chloro-N-(3,4-dichloro­phen­yl)-2-methyl­benzene­sulfonamide

In the title compound, C(13)H(10)Cl(3)NO(2)S, the N—C bond in the C—SO(2)—NH—C segment forms trans and gauche torsion angles with respect to the S=O bonds. Further, the N—H bond in the C—SO(2)—NH—C segment is anti to the meta-Cl atom in the anilino benzene ring and nearly syn with respect to the ort...

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Detalles Bibliográficos
Autores principales: Rodrigues, Vinola Z., Foro, Sabine, Gowda, B. Thimme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247351/
https://www.ncbi.nlm.nih.gov/pubmed/22219969
http://dx.doi.org/10.1107/S1600536811041717
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author Rodrigues, Vinola Z.
Foro, Sabine
Gowda, B. Thimme
author_facet Rodrigues, Vinola Z.
Foro, Sabine
Gowda, B. Thimme
author_sort Rodrigues, Vinola Z.
collection PubMed
description In the title compound, C(13)H(10)Cl(3)NO(2)S, the N—C bond in the C—SO(2)—NH—C segment forms trans and gauche torsion angles with respect to the S=O bonds. Further, the N—H bond in the C—SO(2)—NH—C segment is anti to the meta-Cl atom in the anilino benzene ring and nearly syn with respect to the ortho-methyl group in the sulfonyl benzene ring. The C—SO(2)—NH—C torsion angle is −49.4 (2)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 54.6 (1)°. In the crystal, mol­ecules are linked into chains along the c-axis direction by inter­molecular N—H⋯O hydrogen bonds.
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spelling pubmed-32473512012-01-04 4-Chloro-N-(3,4-dichloro­phen­yl)-2-methyl­benzene­sulfonamide Rodrigues, Vinola Z. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(10)Cl(3)NO(2)S, the N—C bond in the C—SO(2)—NH—C segment forms trans and gauche torsion angles with respect to the S=O bonds. Further, the N—H bond in the C—SO(2)—NH—C segment is anti to the meta-Cl atom in the anilino benzene ring and nearly syn with respect to the ortho-methyl group in the sulfonyl benzene ring. The C—SO(2)—NH—C torsion angle is −49.4 (2)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 54.6 (1)°. In the crystal, mol­ecules are linked into chains along the c-axis direction by inter­molecular N—H⋯O hydrogen bonds. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3247351/ /pubmed/22219969 http://dx.doi.org/10.1107/S1600536811041717 Text en © Rodrigues et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rodrigues, Vinola Z.
Foro, Sabine
Gowda, B. Thimme
4-Chloro-N-(3,4-dichloro­phen­yl)-2-methyl­benzene­sulfonamide
title 4-Chloro-N-(3,4-dichloro­phen­yl)-2-methyl­benzene­sulfonamide
title_full 4-Chloro-N-(3,4-dichloro­phen­yl)-2-methyl­benzene­sulfonamide
title_fullStr 4-Chloro-N-(3,4-dichloro­phen­yl)-2-methyl­benzene­sulfonamide
title_full_unstemmed 4-Chloro-N-(3,4-dichloro­phen­yl)-2-methyl­benzene­sulfonamide
title_short 4-Chloro-N-(3,4-dichloro­phen­yl)-2-methyl­benzene­sulfonamide
title_sort 4-chloro-n-(3,4-dichloro­phen­yl)-2-methyl­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247351/
https://www.ncbi.nlm.nih.gov/pubmed/22219969
http://dx.doi.org/10.1107/S1600536811041717
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