Cargando…
[(2R,3S,5R)-3-Acetoxy-5-(5-formyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-1-yl)-2,3,4,5-tetrahydrofuran-2-yl]methyl acetate
In the two independent but very similar molecules (A and B) of the title compound, C(14)H(16)N(2)O(8), both six-membered pyrimidine rings are nearly planar [maximum deviations = 0.010 (3) Å in A and 0.028 (3) Å in B]. The five-membered furanose ring in molecule A adopts an envelope conformation,...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247360/ https://www.ncbi.nlm.nih.gov/pubmed/22219978 http://dx.doi.org/10.1107/S1600536811041304 |
Sumario: | In the two independent but very similar molecules (A and B) of the title compound, C(14)H(16)N(2)O(8), both six-membered pyrimidine rings are nearly planar [maximum deviations = 0.010 (3) Å in A and 0.028 (3) Å in B]. The five-membered furanose ring in molecule A adopts an envelope conformation, while the same ring in molecule B has a twisted conformation. In the crystal, the A molecules are linked via a pair of intermolecular N—H⋯O hydrogen bonds, forming dimers. Each A molecule is further linked to a B molecule via a second N—H⋯O hydrogen bond. There are also a number of C—H⋯·O interactions present, leading to the formation of a three-dimensional network. |
---|