N-Butyl-4,6-diphenyl­pyrimidin-2-amine

In the title compound, C(20)H(21)N(3), the pyrimidine ring is inclined at dihedral angles of 51.57 (4) and 2.49 (4)° to the two phenyl rings. The dihedral angle between the two terminal phenyl rings is 50.44 (4)°. In the crystal, adjacent mol­ecules are linked via a pair of N—H⋯N hydrogen bonds, for...

Descripción completa

Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Hemamalini, Madhukar, Hazra, Anita, Goswami, Shyamaprosad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247364/
https://www.ncbi.nlm.nih.gov/pubmed/22219982
http://dx.doi.org/10.1107/S160053681104147X
_version_ 1782220090336346112
author Fun, Hoong-Kun
Hemamalini, Madhukar
Hazra, Anita
Goswami, Shyamaprosad
author_facet Fun, Hoong-Kun
Hemamalini, Madhukar
Hazra, Anita
Goswami, Shyamaprosad
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(20)H(21)N(3), the pyrimidine ring is inclined at dihedral angles of 51.57 (4) and 2.49 (4)° to the two phenyl rings. The dihedral angle between the two terminal phenyl rings is 50.44 (4)°. In the crystal, adjacent mol­ecules are linked via a pair of N—H⋯N hydrogen bonds, forming an inversion dimer with an R (2) (2)(8) ring motif. Furthermore, the crystal structure is stabilized by a weak π–π inter­action, with a centroid–centroid distance of 3.6065 (5) Å.
format Online
Article
Text
id pubmed-3247364
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32473642012-01-04 N-Butyl-4,6-diphenyl­pyrimidin-2-amine Fun, Hoong-Kun Hemamalini, Madhukar Hazra, Anita Goswami, Shyamaprosad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(21)N(3), the pyrimidine ring is inclined at dihedral angles of 51.57 (4) and 2.49 (4)° to the two phenyl rings. The dihedral angle between the two terminal phenyl rings is 50.44 (4)°. In the crystal, adjacent mol­ecules are linked via a pair of N—H⋯N hydrogen bonds, forming an inversion dimer with an R (2) (2)(8) ring motif. Furthermore, the crystal structure is stabilized by a weak π–π inter­action, with a centroid–centroid distance of 3.6065 (5) Å. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3247364/ /pubmed/22219982 http://dx.doi.org/10.1107/S160053681104147X Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Hemamalini, Madhukar
Hazra, Anita
Goswami, Shyamaprosad
N-Butyl-4,6-diphenyl­pyrimidin-2-amine
title N-Butyl-4,6-diphenyl­pyrimidin-2-amine
title_full N-Butyl-4,6-diphenyl­pyrimidin-2-amine
title_fullStr N-Butyl-4,6-diphenyl­pyrimidin-2-amine
title_full_unstemmed N-Butyl-4,6-diphenyl­pyrimidin-2-amine
title_short N-Butyl-4,6-diphenyl­pyrimidin-2-amine
title_sort n-butyl-4,6-diphenyl­pyrimidin-2-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247364/
https://www.ncbi.nlm.nih.gov/pubmed/22219982
http://dx.doi.org/10.1107/S160053681104147X
work_keys_str_mv AT funhoongkun nbutyl46diphenylpyrimidin2amine
AT hemamalinimadhukar nbutyl46diphenylpyrimidin2amine
AT hazraanita nbutyl46diphenylpyrimidin2amine
AT goswamishyamaprosad nbutyl46diphenylpyrimidin2amine

Ejemplares similares