1,3-Bis(2-chloro­phen­yl)thio­urea: a monoclinic polymorph

The title compound, C(13)H(10)Cl(2)N(2)S, represents a monoclinic polymorph of the previously reported ortho­rhom­bic form [Ramnathan et al. (1996 ▶). Acta Cryst. C52, 134–136]. The mol­ecule is twisted with the dihedral angle between the benzene rings being 55.37 (7)°. The N—H atoms are syn to each...

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Detalles Bibliográficos
Autores principales: Yeo, Chien Ing, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247371/
https://www.ncbi.nlm.nih.gov/pubmed/22219989
http://dx.doi.org/10.1107/S1600536811041894
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author Yeo, Chien Ing
Tiekink, Edward R. T.
author_facet Yeo, Chien Ing
Tiekink, Edward R. T.
author_sort Yeo, Chien Ing
collection PubMed
description The title compound, C(13)H(10)Cl(2)N(2)S, represents a monoclinic polymorph of the previously reported ortho­rhom­bic form [Ramnathan et al. (1996 ▶). Acta Cryst. C52, 134–136]. The mol­ecule is twisted with the dihedral angle between the benzene rings being 55.37 (7)°. The N—H atoms are syn to each other, which contrasts their anti disposition in the ortho­rhom­bic form. In the crystal, mol­ecules assemble into zigzag chains along the c axis via N—H⋯S hydrogen bonds. Chains are connected into layers via C—H⋯Cl inter­actions, and these stack along the a axis.
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spelling pubmed-32473712012-01-04 1,3-Bis(2-chloro­phen­yl)thio­urea: a monoclinic polymorph Yeo, Chien Ing Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(10)Cl(2)N(2)S, represents a monoclinic polymorph of the previously reported ortho­rhom­bic form [Ramnathan et al. (1996 ▶). Acta Cryst. C52, 134–136]. The mol­ecule is twisted with the dihedral angle between the benzene rings being 55.37 (7)°. The N—H atoms are syn to each other, which contrasts their anti disposition in the ortho­rhom­bic form. In the crystal, mol­ecules assemble into zigzag chains along the c axis via N—H⋯S hydrogen bonds. Chains are connected into layers via C—H⋯Cl inter­actions, and these stack along the a axis. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3247371/ /pubmed/22219989 http://dx.doi.org/10.1107/S1600536811041894 Text en © Yeo and Tiekink 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yeo, Chien Ing
Tiekink, Edward R. T.
1,3-Bis(2-chloro­phen­yl)thio­urea: a monoclinic polymorph
title 1,3-Bis(2-chloro­phen­yl)thio­urea: a monoclinic polymorph
title_full 1,3-Bis(2-chloro­phen­yl)thio­urea: a monoclinic polymorph
title_fullStr 1,3-Bis(2-chloro­phen­yl)thio­urea: a monoclinic polymorph
title_full_unstemmed 1,3-Bis(2-chloro­phen­yl)thio­urea: a monoclinic polymorph
title_short 1,3-Bis(2-chloro­phen­yl)thio­urea: a monoclinic polymorph
title_sort 1,3-bis(2-chloro­phen­yl)thio­urea: a monoclinic polymorph
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247371/
https://www.ncbi.nlm.nih.gov/pubmed/22219989
http://dx.doi.org/10.1107/S1600536811041894
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AT tiekinkedwardrt 13bis2chlorophenylthioureaamonoclinicpolymorph

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