exo-10,11-Dibromo­tricyclo­[6.3.1.0(2,7)]dodeca-2,4,6,9-tetra­ene

The title compound, C(12)H(10)Br(2), is a bridged ring system based on a homobenzonorbornadiene framework. The exo configuration of one of the Br atoms was previously assigned via NMR correlations and has now been confirmed by the geometry of the solid-state structure. The compound features a Br—C—C...

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Detalles Bibliográficos
Autores principales: Johnson, Kevin R. D., Bender, Christopher O., Boeré, René T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247379/
https://www.ncbi.nlm.nih.gov/pubmed/22219997
http://dx.doi.org/10.1107/S1600536811041730
Descripción
Sumario:The title compound, C(12)H(10)Br(2), is a bridged ring system based on a homobenzonorbornadiene framework. The exo configuration of one of the Br atoms was previously assigned via NMR correlations and has now been confirmed by the geometry of the solid-state structure. The compound features a Br—C—C—Br torsion angle of 66.68 (12)°, whereby the C atoms in the calculation are respectively sp (3)- and sp (2)-hybridized.

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