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(E)-4-Hydroxy-N′-(3,4,5-trimethoxybenzylidene)benzohydrazide
The title benzohydrazide derivative, C(17)H(18)N(2)O(5), exists in a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 19.41 (5)°. The two methoxy groups at the meta positions of the trimethoxybenzene group are almost coplanar with the ring [C...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247387/ https://www.ncbi.nlm.nih.gov/pubmed/22220005 http://dx.doi.org/10.1107/S1600536811041535 |
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author | Horkaew, Jirapa Chantrapromma, Suchada Fun, Hoong-Kun |
author_facet | Horkaew, Jirapa Chantrapromma, Suchada Fun, Hoong-Kun |
author_sort | Horkaew, Jirapa |
collection | PubMed |
description | The title benzohydrazide derivative, C(17)H(18)N(2)O(5), exists in a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 19.41 (5)°. The two methoxy groups at the meta positions of the trimethoxybenzene group are almost coplanar with the ring [C—O—C—C = 1.62 (16) and 178.33 (10)°], whereas the third methoxy group, at the para position, is (+)-synclinal with the ring. In the crystal, molecules are linked by N—H⋯O and bifurcated O—H⋯(N,O) hydrogen bonds, as well as weak C—H⋯O interactions, into sheets lying parallel to the ac plane. A C—H⋯π interaction also occurs. |
format | Online Article Text |
id | pubmed-3247387 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32473872012-01-04 (E)-4-Hydroxy-N′-(3,4,5-trimethoxybenzylidene)benzohydrazide Horkaew, Jirapa Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title benzohydrazide derivative, C(17)H(18)N(2)O(5), exists in a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 19.41 (5)°. The two methoxy groups at the meta positions of the trimethoxybenzene group are almost coplanar with the ring [C—O—C—C = 1.62 (16) and 178.33 (10)°], whereas the third methoxy group, at the para position, is (+)-synclinal with the ring. In the crystal, molecules are linked by N—H⋯O and bifurcated O—H⋯(N,O) hydrogen bonds, as well as weak C—H⋯O interactions, into sheets lying parallel to the ac plane. A C—H⋯π interaction also occurs. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3247387/ /pubmed/22220005 http://dx.doi.org/10.1107/S1600536811041535 Text en © Horkaew et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Horkaew, Jirapa Chantrapromma, Suchada Fun, Hoong-Kun (E)-4-Hydroxy-N′-(3,4,5-trimethoxybenzylidene)benzohydrazide |
title | (E)-4-Hydroxy-N′-(3,4,5-trimethoxybenzylidene)benzohydrazide |
title_full | (E)-4-Hydroxy-N′-(3,4,5-trimethoxybenzylidene)benzohydrazide |
title_fullStr | (E)-4-Hydroxy-N′-(3,4,5-trimethoxybenzylidene)benzohydrazide |
title_full_unstemmed | (E)-4-Hydroxy-N′-(3,4,5-trimethoxybenzylidene)benzohydrazide |
title_short | (E)-4-Hydroxy-N′-(3,4,5-trimethoxybenzylidene)benzohydrazide |
title_sort | (e)-4-hydroxy-n′-(3,4,5-trimethoxybenzylidene)benzohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247387/ https://www.ncbi.nlm.nih.gov/pubmed/22220005 http://dx.doi.org/10.1107/S1600536811041535 |
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