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(E)-4-Hy­droxy-N′-(3,4,5-trimeth­oxy­benzyl­idene)benzohydrazide

The title benzohydrazide derivative, C(17)H(18)N(2)O(5), exists in a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 19.41 (5)°. The two meth­oxy groups at the meta positions of the trimeth­oxy­benzene group are almost coplanar with the ring [C...

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Detalles Bibliográficos
Autores principales: Horkaew, Jirapa, Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247387/
https://www.ncbi.nlm.nih.gov/pubmed/22220005
http://dx.doi.org/10.1107/S1600536811041535
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author Horkaew, Jirapa
Chantrapromma, Suchada
Fun, Hoong-Kun
author_facet Horkaew, Jirapa
Chantrapromma, Suchada
Fun, Hoong-Kun
author_sort Horkaew, Jirapa
collection PubMed
description The title benzohydrazide derivative, C(17)H(18)N(2)O(5), exists in a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 19.41 (5)°. The two meth­oxy groups at the meta positions of the trimeth­oxy­benzene group are almost coplanar with the ring [C—O—C—C = 1.62 (16) and 178.33 (10)°], whereas the third meth­oxy group, at the para position, is (+)-synclinal with the ring. In the crystal, mol­ecules are linked by N—H⋯O and bifurcated O—H⋯(N,O) hydrogen bonds, as well as weak C—H⋯O inter­actions, into sheets lying parallel to the ac plane. A C—H⋯π inter­action also occurs.
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spelling pubmed-32473872012-01-04 (E)-4-Hy­droxy-N′-(3,4,5-trimeth­oxy­benzyl­idene)benzohydrazide Horkaew, Jirapa Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title benzohydrazide derivative, C(17)H(18)N(2)O(5), exists in a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 19.41 (5)°. The two meth­oxy groups at the meta positions of the trimeth­oxy­benzene group are almost coplanar with the ring [C—O—C—C = 1.62 (16) and 178.33 (10)°], whereas the third meth­oxy group, at the para position, is (+)-synclinal with the ring. In the crystal, mol­ecules are linked by N—H⋯O and bifurcated O—H⋯(N,O) hydrogen bonds, as well as weak C—H⋯O inter­actions, into sheets lying parallel to the ac plane. A C—H⋯π inter­action also occurs. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3247387/ /pubmed/22220005 http://dx.doi.org/10.1107/S1600536811041535 Text en © Horkaew et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Horkaew, Jirapa
Chantrapromma, Suchada
Fun, Hoong-Kun
(E)-4-Hy­droxy-N′-(3,4,5-trimeth­oxy­benzyl­idene)benzohydrazide
title (E)-4-Hy­droxy-N′-(3,4,5-trimeth­oxy­benzyl­idene)benzohydrazide
title_full (E)-4-Hy­droxy-N′-(3,4,5-trimeth­oxy­benzyl­idene)benzohydrazide
title_fullStr (E)-4-Hy­droxy-N′-(3,4,5-trimeth­oxy­benzyl­idene)benzohydrazide
title_full_unstemmed (E)-4-Hy­droxy-N′-(3,4,5-trimeth­oxy­benzyl­idene)benzohydrazide
title_short (E)-4-Hy­droxy-N′-(3,4,5-trimeth­oxy­benzyl­idene)benzohydrazide
title_sort (e)-4-hy­droxy-n′-(3,4,5-trimeth­oxy­benzyl­idene)benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247387/
https://www.ncbi.nlm.nih.gov/pubmed/22220005
http://dx.doi.org/10.1107/S1600536811041535
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