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N,N′-(Ethane-1,2-diyldi-o-phenylene)bis(pyridine-2-carboxamide)
The title molecule, C(26)H(22)N(4)O(2), is centrosymmetric and adopts an anti conformation. Two intramolecular hydrogen bonds, viz. amide–pyridine N—H⋯N and phenyl–amide C—H⋯O, stabilize the trans conformation of the (pyridine-2-carboxamido)phenyl group about the amide plane. In the crystal, the...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247390/ https://www.ncbi.nlm.nih.gov/pubmed/22220008 http://dx.doi.org/10.1107/S1600536811042309 |
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author | Sarkar, Shuranjan Lee, Hong-In |
author_facet | Sarkar, Shuranjan Lee, Hong-In |
author_sort | Sarkar, Shuranjan |
collection | PubMed |
description | The title molecule, C(26)H(22)N(4)O(2), is centrosymmetric and adopts an anti conformation. Two intramolecular hydrogen bonds, viz. amide–pyridine N—H⋯N and phenyl–amide C—H⋯O, stabilize the trans conformation of the (pyridine-2-carboxamido)phenyl group about the amide plane. In the crystal, the presence of weak intermolecular C—H⋯O hydrogen bonds results in the formation of a three-dimensional network. |
format | Online Article Text |
id | pubmed-3247390 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32473902012-01-04 N,N′-(Ethane-1,2-diyldi-o-phenylene)bis(pyridine-2-carboxamide) Sarkar, Shuranjan Lee, Hong-In Acta Crystallogr Sect E Struct Rep Online Organic Papers The title molecule, C(26)H(22)N(4)O(2), is centrosymmetric and adopts an anti conformation. Two intramolecular hydrogen bonds, viz. amide–pyridine N—H⋯N and phenyl–amide C—H⋯O, stabilize the trans conformation of the (pyridine-2-carboxamido)phenyl group about the amide plane. In the crystal, the presence of weak intermolecular C—H⋯O hydrogen bonds results in the formation of a three-dimensional network. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3247390/ /pubmed/22220008 http://dx.doi.org/10.1107/S1600536811042309 Text en © Sarkar and Lee 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sarkar, Shuranjan Lee, Hong-In N,N′-(Ethane-1,2-diyldi-o-phenylene)bis(pyridine-2-carboxamide) |
title |
N,N′-(Ethane-1,2-diyldi-o-phenylene)bis(pyridine-2-carboxamide) |
title_full |
N,N′-(Ethane-1,2-diyldi-o-phenylene)bis(pyridine-2-carboxamide) |
title_fullStr |
N,N′-(Ethane-1,2-diyldi-o-phenylene)bis(pyridine-2-carboxamide) |
title_full_unstemmed |
N,N′-(Ethane-1,2-diyldi-o-phenylene)bis(pyridine-2-carboxamide) |
title_short |
N,N′-(Ethane-1,2-diyldi-o-phenylene)bis(pyridine-2-carboxamide) |
title_sort | n,n′-(ethane-1,2-diyldi-o-phenylene)bis(pyridine-2-carboxamide) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247390/ https://www.ncbi.nlm.nih.gov/pubmed/22220008 http://dx.doi.org/10.1107/S1600536811042309 |
work_keys_str_mv | AT sarkarshuranjan nnethane12diyldiophenylenebispyridine2carboxamide AT leehongin nnethane12diyldiophenylenebispyridine2carboxamide |