N′-(5-Bromo-2-hy­droxy­benzyl­idene)-3-nitro­benzohydrazide methanol mono­solvate

In the title compound, C(14)H(10)BrN(3)O(4)·CH(4)O, the dihedral angle between the two benzene rings in the hydrazone mol­ecule is 5.8 (3)° and an intra­molecular O—H⋯N hydrogen bond generates an S(6) ring motif. An O—H⋯O hydrogen bond occurs between the hydrazone mol­ecule and the methanol solvent...

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Autor principal: Tang, Chun-Bao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247402/
https://www.ncbi.nlm.nih.gov/pubmed/22220020
http://dx.doi.org/10.1107/S1600536811042553
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author Tang, Chun-Bao
author_facet Tang, Chun-Bao
author_sort Tang, Chun-Bao
collection PubMed
description In the title compound, C(14)H(10)BrN(3)O(4)·CH(4)O, the dihedral angle between the two benzene rings in the hydrazone mol­ecule is 5.8 (3)° and an intra­molecular O—H⋯N hydrogen bond generates an S(6) ring motif. An O—H⋯O hydrogen bond occurs between the hydrazone mol­ecule and the methanol solvent mol­ecule. In the crystal, the components are linked by inter­molecular N—H⋯O hydrogen bonds, forming chains along the a axis.
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spelling pubmed-32474022012-01-04 N′-(5-Bromo-2-hy­droxy­benzyl­idene)-3-nitro­benzohydrazide methanol mono­solvate Tang, Chun-Bao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(10)BrN(3)O(4)·CH(4)O, the dihedral angle between the two benzene rings in the hydrazone mol­ecule is 5.8 (3)° and an intra­molecular O—H⋯N hydrogen bond generates an S(6) ring motif. An O—H⋯O hydrogen bond occurs between the hydrazone mol­ecule and the methanol solvent mol­ecule. In the crystal, the components are linked by inter­molecular N—H⋯O hydrogen bonds, forming chains along the a axis. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3247402/ /pubmed/22220020 http://dx.doi.org/10.1107/S1600536811042553 Text en © Chun-Bao Tang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tang, Chun-Bao
N′-(5-Bromo-2-hy­droxy­benzyl­idene)-3-nitro­benzohydrazide methanol mono­solvate
title N′-(5-Bromo-2-hy­droxy­benzyl­idene)-3-nitro­benzohydrazide methanol mono­solvate
title_full N′-(5-Bromo-2-hy­droxy­benzyl­idene)-3-nitro­benzohydrazide methanol mono­solvate
title_fullStr N′-(5-Bromo-2-hy­droxy­benzyl­idene)-3-nitro­benzohydrazide methanol mono­solvate
title_full_unstemmed N′-(5-Bromo-2-hy­droxy­benzyl­idene)-3-nitro­benzohydrazide methanol mono­solvate
title_short N′-(5-Bromo-2-hy­droxy­benzyl­idene)-3-nitro­benzohydrazide methanol mono­solvate
title_sort n′-(5-bromo-2-hy­droxy­benzyl­idene)-3-nitro­benzohydrazide methanol mono­solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247402/
https://www.ncbi.nlm.nih.gov/pubmed/22220020
http://dx.doi.org/10.1107/S1600536811042553
work_keys_str_mv AT tangchunbao n5bromo2hydroxybenzylidene3nitrobenzohydrazidemethanolmonosolvate

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