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4-(3-Fluorophenyl)-1-(propan-2-ylidene)thiosemicarbazone
The title compound, C(10)H(12)FN(3)S, crystallizes in the same space group (P2(1)/c) as two polymorphic forms of 4-phenyl-1-(propan-2-ylidene)thiosemicarbazone [Jian et al. (2005). Acta Cryst. E61, o653–o654; Venkatraman et al. (2005). Acta Cryst. E61, o3914–o3916]. The arrangement of molecules r...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247409/ https://www.ncbi.nlm.nih.gov/pubmed/22220027 http://dx.doi.org/10.1107/S1600536811042504 |
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author | Miroslaw, Barbara Szulczyk, Daniel Koziol, Anna E. Struga, Marta |
author_facet | Miroslaw, Barbara Szulczyk, Daniel Koziol, Anna E. Struga, Marta |
author_sort | Miroslaw, Barbara |
collection | PubMed |
description | The title compound, C(10)H(12)FN(3)S, crystallizes in the same space group (P2(1)/c) as two polymorphic forms of 4-phenyl-1-(propan-2-ylidene)thiosemicarbazone [Jian et al. (2005). Acta Cryst. E61, o653–o654; Venkatraman et al. (2005). Acta Cryst. E61, o3914–o3916]. The arrangement of molecules relative to the twofold screw axes is similar to that in the crystal structure of the lower density polymorph. In the solid state, the molecular conformation is stabilized by an intramolecular N—H⋯N hydrogen bond. The molecules form centrosymmetric R (2) (2)(8) dimers in the crystal through pairs of N—H⋯S hydrogen bonds. |
format | Online Article Text |
id | pubmed-3247409 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32474092012-01-04 4-(3-Fluorophenyl)-1-(propan-2-ylidene)thiosemicarbazone Miroslaw, Barbara Szulczyk, Daniel Koziol, Anna E. Struga, Marta Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(12)FN(3)S, crystallizes in the same space group (P2(1)/c) as two polymorphic forms of 4-phenyl-1-(propan-2-ylidene)thiosemicarbazone [Jian et al. (2005). Acta Cryst. E61, o653–o654; Venkatraman et al. (2005). Acta Cryst. E61, o3914–o3916]. The arrangement of molecules relative to the twofold screw axes is similar to that in the crystal structure of the lower density polymorph. In the solid state, the molecular conformation is stabilized by an intramolecular N—H⋯N hydrogen bond. The molecules form centrosymmetric R (2) (2)(8) dimers in the crystal through pairs of N—H⋯S hydrogen bonds. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3247409/ /pubmed/22220027 http://dx.doi.org/10.1107/S1600536811042504 Text en © Miroslaw et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Miroslaw, Barbara Szulczyk, Daniel Koziol, Anna E. Struga, Marta 4-(3-Fluorophenyl)-1-(propan-2-ylidene)thiosemicarbazone |
title | 4-(3-Fluorophenyl)-1-(propan-2-ylidene)thiosemicarbazone |
title_full | 4-(3-Fluorophenyl)-1-(propan-2-ylidene)thiosemicarbazone |
title_fullStr | 4-(3-Fluorophenyl)-1-(propan-2-ylidene)thiosemicarbazone |
title_full_unstemmed | 4-(3-Fluorophenyl)-1-(propan-2-ylidene)thiosemicarbazone |
title_short | 4-(3-Fluorophenyl)-1-(propan-2-ylidene)thiosemicarbazone |
title_sort | 4-(3-fluorophenyl)-1-(propan-2-ylidene)thiosemicarbazone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247409/ https://www.ncbi.nlm.nih.gov/pubmed/22220027 http://dx.doi.org/10.1107/S1600536811042504 |
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