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4-(3-Fluoro­phen­yl)-1-(propan-2-yl­idene)thio­semicarbazone

The title compound, C(10)H(12)FN(3)S, crystallizes in the same space group (P2(1)/c) as two polymorphic forms of 4-phenyl-1-(propan-2-yl­idene)thio­semicarbazone [Jian et al. (2005). Acta Cryst. E61, o653–o654; Venkatraman et al. (2005). Acta Cryst. E61, o3914–o3916]. The arrangement of mol­ecules r...

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Detalles Bibliográficos
Autores principales: Miroslaw, Barbara, Szulczyk, Daniel, Koziol, Anna E., Struga, Marta
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247409/
https://www.ncbi.nlm.nih.gov/pubmed/22220027
http://dx.doi.org/10.1107/S1600536811042504
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author Miroslaw, Barbara
Szulczyk, Daniel
Koziol, Anna E.
Struga, Marta
author_facet Miroslaw, Barbara
Szulczyk, Daniel
Koziol, Anna E.
Struga, Marta
author_sort Miroslaw, Barbara
collection PubMed
description The title compound, C(10)H(12)FN(3)S, crystallizes in the same space group (P2(1)/c) as two polymorphic forms of 4-phenyl-1-(propan-2-yl­idene)thio­semicarbazone [Jian et al. (2005). Acta Cryst. E61, o653–o654; Venkatraman et al. (2005). Acta Cryst. E61, o3914–o3916]. The arrangement of mol­ecules relative to the twofold screw axes is similar to that in the crystal structure of the lower density polymorph. In the solid state, the mol­ecular conformation is stabilized by an intra­molecular N—H⋯N hydrogen bond. The mol­ecules form centrosymmetric R (2) (2)(8) dimers in the crystal through pairs of N—H⋯S hydrogen bonds.
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spelling pubmed-32474092012-01-04 4-(3-Fluoro­phen­yl)-1-(propan-2-yl­idene)thio­semicarbazone Miroslaw, Barbara Szulczyk, Daniel Koziol, Anna E. Struga, Marta Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(12)FN(3)S, crystallizes in the same space group (P2(1)/c) as two polymorphic forms of 4-phenyl-1-(propan-2-yl­idene)thio­semicarbazone [Jian et al. (2005). Acta Cryst. E61, o653–o654; Venkatraman et al. (2005). Acta Cryst. E61, o3914–o3916]. The arrangement of mol­ecules relative to the twofold screw axes is similar to that in the crystal structure of the lower density polymorph. In the solid state, the mol­ecular conformation is stabilized by an intra­molecular N—H⋯N hydrogen bond. The mol­ecules form centrosymmetric R (2) (2)(8) dimers in the crystal through pairs of N—H⋯S hydrogen bonds. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3247409/ /pubmed/22220027 http://dx.doi.org/10.1107/S1600536811042504 Text en © Miroslaw et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Miroslaw, Barbara
Szulczyk, Daniel
Koziol, Anna E.
Struga, Marta
4-(3-Fluoro­phen­yl)-1-(propan-2-yl­idene)thio­semicarbazone
title 4-(3-Fluoro­phen­yl)-1-(propan-2-yl­idene)thio­semicarbazone
title_full 4-(3-Fluoro­phen­yl)-1-(propan-2-yl­idene)thio­semicarbazone
title_fullStr 4-(3-Fluoro­phen­yl)-1-(propan-2-yl­idene)thio­semicarbazone
title_full_unstemmed 4-(3-Fluoro­phen­yl)-1-(propan-2-yl­idene)thio­semicarbazone
title_short 4-(3-Fluoro­phen­yl)-1-(propan-2-yl­idene)thio­semicarbazone
title_sort 4-(3-fluoro­phen­yl)-1-(propan-2-yl­idene)thio­semicarbazone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247409/
https://www.ncbi.nlm.nih.gov/pubmed/22220027
http://dx.doi.org/10.1107/S1600536811042504
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