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Benzyl (E)-3-(4-methoxybenzylidene)dithiocarbazate
The title compound, C(16)H(16)N(2)OS(2), was obtained from a condensation reaction of benzyl dithiocarbazate and 4-methoxybenzaldehyde. In the molecule, the methoxyphenyl ring and dithiocarbazate fragment are located on opposite sides of the C=N double bond, showing an E configuration. The di...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247410/ https://www.ncbi.nlm.nih.gov/pubmed/22220028 http://dx.doi.org/10.1107/S1600536811042140 |
Sumario: | The title compound, C(16)H(16)N(2)OS(2), was obtained from a condensation reaction of benzyl dithiocarbazate and 4-methoxybenzaldehyde. In the molecule, the methoxyphenyl ring and dithiocarbazate fragment are located on opposite sides of the C=N double bond, showing an E configuration. The dithiocarbazate fragment is approximately planar (r.m.s. deviation = 0.0052 Å); its mean plane is oriented at dihedral angles of 8.19 (15) and 85.70 (13)°, respectively, to the methoxyphenyl and phenyl rings. Intermolecular N—H⋯S hydrogen bonds and weak C—H⋯π interactions are observed in the crystal structure. |
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