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Benzyl (E)-3-(4-meth­oxy­benzyl­idene)dithio­carbazate

The title compound, C(16)H(16)N(2)OS(2), was obtained from a condensation reaction of benzyl dithio­carbazate and 4-meth­oxy­benzaldehyde. In the mol­ecule, the meth­oxy­phenyl ring and dithio­carbazate fragment are located on opposite sides of the C=N double bond, showing an E configuration. The di...

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Detalles Bibliográficos
Autores principales: Fan, Zheng, Huang, Yan-Lan, Wang, Zhao, Guo, Han-Qi, Shan, Shang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247410/
https://www.ncbi.nlm.nih.gov/pubmed/22220028
http://dx.doi.org/10.1107/S1600536811042140
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author Fan, Zheng
Huang, Yan-Lan
Wang, Zhao
Guo, Han-Qi
Shan, Shang
author_facet Fan, Zheng
Huang, Yan-Lan
Wang, Zhao
Guo, Han-Qi
Shan, Shang
author_sort Fan, Zheng
collection PubMed
description The title compound, C(16)H(16)N(2)OS(2), was obtained from a condensation reaction of benzyl dithio­carbazate and 4-meth­oxy­benzaldehyde. In the mol­ecule, the meth­oxy­phenyl ring and dithio­carbazate fragment are located on opposite sides of the C=N double bond, showing an E configuration. The dithio­carbazate fragment is approximately planar (r.m.s. deviation = 0.0052 Å); its mean plane is oriented at dihedral angles of 8.19 (15) and 85.70 (13)°, respectively, to the meth­oxy­phenyl and phenyl rings. Inter­molecular N—H⋯S hydrogen bonds and weak C—H⋯π inter­actions are observed in the crystal structure.
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spelling pubmed-32474102012-01-04 Benzyl (E)-3-(4-meth­oxy­benzyl­idene)dithio­carbazate Fan, Zheng Huang, Yan-Lan Wang, Zhao Guo, Han-Qi Shan, Shang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(16)N(2)OS(2), was obtained from a condensation reaction of benzyl dithio­carbazate and 4-meth­oxy­benzaldehyde. In the mol­ecule, the meth­oxy­phenyl ring and dithio­carbazate fragment are located on opposite sides of the C=N double bond, showing an E configuration. The dithio­carbazate fragment is approximately planar (r.m.s. deviation = 0.0052 Å); its mean plane is oriented at dihedral angles of 8.19 (15) and 85.70 (13)°, respectively, to the meth­oxy­phenyl and phenyl rings. Inter­molecular N—H⋯S hydrogen bonds and weak C—H⋯π inter­actions are observed in the crystal structure. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3247410/ /pubmed/22220028 http://dx.doi.org/10.1107/S1600536811042140 Text en © Fan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fan, Zheng
Huang, Yan-Lan
Wang, Zhao
Guo, Han-Qi
Shan, Shang
Benzyl (E)-3-(4-meth­oxy­benzyl­idene)dithio­carbazate
title Benzyl (E)-3-(4-meth­oxy­benzyl­idene)dithio­carbazate
title_full Benzyl (E)-3-(4-meth­oxy­benzyl­idene)dithio­carbazate
title_fullStr Benzyl (E)-3-(4-meth­oxy­benzyl­idene)dithio­carbazate
title_full_unstemmed Benzyl (E)-3-(4-meth­oxy­benzyl­idene)dithio­carbazate
title_short Benzyl (E)-3-(4-meth­oxy­benzyl­idene)dithio­carbazate
title_sort benzyl (e)-3-(4-meth­oxy­benzyl­idene)dithio­carbazate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247410/
https://www.ncbi.nlm.nih.gov/pubmed/22220028
http://dx.doi.org/10.1107/S1600536811042140
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