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Benzyl (E)-3-(2-bromo-5-meth­oxy­benzyl­idene)dithio­carbazate

The title compound, C(16)H(15)BrN(2)OS(2), was obtained from the condensation reaction of benzyl dithio­carbazate and 2-bromo-5-meth­oxy­lbenzaldehyde. In the mol­ecule, the bromo­meth­oxy­phenyl ring and dithio­carbazate fragment are located on the opposite sides of the C=N double bond, showing the...

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Detalles Bibliográficos
Autores principales: Fan, Zheng, Huang, Yan-Lan, Wang, Zhao, Guo, Han-Qi, Shan, Shang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247414/
https://www.ncbi.nlm.nih.gov/pubmed/22220032
http://dx.doi.org/10.1107/S1600536811042826
Descripción
Sumario:The title compound, C(16)H(15)BrN(2)OS(2), was obtained from the condensation reaction of benzyl dithio­carbazate and 2-bromo-5-meth­oxy­lbenzaldehyde. In the mol­ecule, the bromo­meth­oxy­phenyl ring and dithio­carbazate fragment are located on the opposite sides of the C=N double bond, showing the E conformation. The dithio­carbazate fragment is approximately planar (r.m.s deviation 0.0187 Å); its mean plane is oriented with respect to the bromo­meth­oxy­phenyl and phenyl rings at 7.60 (12) and 60.08 (9)°, respectively. In the crystal, inversion dimers linked by pairs of N—H⋯S hydrogen bonds occur. A short Br⋯Br contact of 3.5526 (12) Å is observed in the crystal structure.