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1,1′-{2,2′-[1,4-Phenylenebis(methylene)]bis(oxy)bis(2,1-phenylene)}diethanone
The asymmetric unit of the title compound, C(24)H(22)O(4), contains one half-molecule, the other half being generated by a crystallographic center of inversion. The central benzene ring makes a dihedral angle of 72.49 (5)° with the terminal benzene ring. In the crystal, adjacent molecules are link...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247415/ https://www.ncbi.nlm.nih.gov/pubmed/22220033 http://dx.doi.org/10.1107/S1600536811042528 |
Sumario: | The asymmetric unit of the title compound, C(24)H(22)O(4), contains one half-molecule, the other half being generated by a crystallographic center of inversion. The central benzene ring makes a dihedral angle of 72.49 (5)° with the terminal benzene ring. In the crystal, adjacent molecules are linked through C—H⋯O interactions, forming a sheet structure parallel to the bc plane. The sheets are stacked along the a axis via π–π interactions formed between the terminal benzene rings [centroid–centroid separation = 3.7276 (6) Å]. |
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