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1,1′,1′′-{[4-(3,4-Ethyl­ene­dioxy­thio­phen-2-yl)phen­yl]methane­tri­yl}tris­(1H-pyra­zole)

In the title complex, C(22)H(18)N(6)O(2)S, two of the pyrazole rings are disordered over two sets of sites with ratios of refined occupancies of 0.58 (2):0.42 (2) and 0.517 (12):0.483 (12). The dioxane ring is in a half-chair conformation and the two –CH(2)– groups of this ring are disordered over t...

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Detalles Bibliográficos
Autores principales: Chen, Xiao-Yan, Yang, Xiaoping, Holliday, Bradley J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247419/
https://www.ncbi.nlm.nih.gov/pubmed/22220037
http://dx.doi.org/10.1107/S160053681104253X
Descripción
Sumario:In the title complex, C(22)H(18)N(6)O(2)S, two of the pyrazole rings are disordered over two sets of sites with ratios of refined occupancies of 0.58 (2):0.42 (2) and 0.517 (12):0.483 (12). The dioxane ring is in a half-chair conformation and the two –CH(2)– groups of this ring are disordered over two sets of sites, the ratio of refined occupancies being 0.855 (19):0.145 (19). The essentially planar thio­phene ring [largest deviation = 0.0444 (2) Å] forms a dihedral angle of 19.59 (3)° with the benzene ring.