N,N′-Dicyclo­hexyl-N′′-(2,6-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide

In the title mol­ecule, C(21)H(32)F(2)N(3)O(2)P, the P=O and N—H groups are syn with respect to each other, and the P atom is bonded in a distorted tetra­hedral environment. The phosphoryl group adopts an anti orientation with respect to the carbonyl group. The angles at the tertiary N atoms (with b...

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Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Tarahhomi, Atekeh, Rheingold, Arnold L., Golen, James A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247423/
https://www.ncbi.nlm.nih.gov/pubmed/22220041
http://dx.doi.org/10.1107/S1600536811043029
Descripción
Sumario:In the title mol­ecule, C(21)H(32)F(2)N(3)O(2)P, the P=O and N—H groups are syn with respect to each other, and the P atom is bonded in a distorted tetra­hedral environment. The phosphoryl group adopts an anti orientation with respect to the carbonyl group. The angles at the tertiary N atoms (with bond-angle sums of 358.4 and 357.0°) confirm their sp (2) character. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops.

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