N,N′-Dicyclo­hexyl-N′′-(2,6-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide

In the title mol­ecule, C(21)H(32)F(2)N(3)O(2)P, the P=O and N—H groups are syn with respect to each other, and the P atom is bonded in a distorted tetra­hedral environment. The phosphoryl group adopts an anti orientation with respect to the carbonyl group. The angles at the tertiary N atoms (with b...

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Autores principales: Pourayoubi, Mehrdad, Tarahhomi, Atekeh, Rheingold, Arnold L., Golen, James A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247423/
https://www.ncbi.nlm.nih.gov/pubmed/22220041
http://dx.doi.org/10.1107/S1600536811043029
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author Pourayoubi, Mehrdad
Tarahhomi, Atekeh
Rheingold, Arnold L.
Golen, James A.
author_facet Pourayoubi, Mehrdad
Tarahhomi, Atekeh
Rheingold, Arnold L.
Golen, James A.
author_sort Pourayoubi, Mehrdad
collection PubMed
description In the title mol­ecule, C(21)H(32)F(2)N(3)O(2)P, the P=O and N—H groups are syn with respect to each other, and the P atom is bonded in a distorted tetra­hedral environment. The phosphoryl group adopts an anti orientation with respect to the carbonyl group. The angles at the tertiary N atoms (with bond-angle sums of 358.4 and 357.0°) confirm their sp (2) character. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops.
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spelling pubmed-32474232012-01-04 N,N′-Dicyclo­hexyl-N′′-(2,6-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide Pourayoubi, Mehrdad Tarahhomi, Atekeh Rheingold, Arnold L. Golen, James A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(21)H(32)F(2)N(3)O(2)P, the P=O and N—H groups are syn with respect to each other, and the P atom is bonded in a distorted tetra­hedral environment. The phosphoryl group adopts an anti orientation with respect to the carbonyl group. The angles at the tertiary N atoms (with bond-angle sums of 358.4 and 357.0°) confirm their sp (2) character. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3247423/ /pubmed/22220041 http://dx.doi.org/10.1107/S1600536811043029 Text en © Pourayoubi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pourayoubi, Mehrdad
Tarahhomi, Atekeh
Rheingold, Arnold L.
Golen, James A.
N,N′-Dicyclo­hexyl-N′′-(2,6-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide
title N,N′-Dicyclo­hexyl-N′′-(2,6-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide
title_full N,N′-Dicyclo­hexyl-N′′-(2,6-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide
title_fullStr N,N′-Dicyclo­hexyl-N′′-(2,6-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide
title_full_unstemmed N,N′-Dicyclo­hexyl-N′′-(2,6-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide
title_short N,N′-Dicyclo­hexyl-N′′-(2,6-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide
title_sort n,n′-dicyclo­hexyl-n′′-(2,6-difluoro­benzo­yl)-n,n′-dimethyl­phospho­ric triamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247423/
https://www.ncbi.nlm.nih.gov/pubmed/22220041
http://dx.doi.org/10.1107/S1600536811043029
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