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2-Nitroanilinium bromide
The title compound, C(6)H(7)N(2)O(2) (+)·Br(−), is isomorphous with 2-nitroanilinium chloride and contains an characteristic intramolecular N—H⋯O hydrogen bond, forming an S(6) motif. Intermolecular N—H⋯Br hydrogen bonds occur in the crystal structure. Two zigzag chains of C (2) (1)(4) motifs ext...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247429/ https://www.ncbi.nlm.nih.gov/pubmed/22220047 http://dx.doi.org/10.1107/S1600536811041948 |
| _version_ | 1782220105094004736 |
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| author | Anitha, R. Athimoolam, S. Bahadur, S. Asath Gunasekaran, M. |
| author_facet | Anitha, R. Athimoolam, S. Bahadur, S. Asath Gunasekaran, M. |
| author_sort | Anitha, R. |
| collection | PubMed |
| description | The title compound, C(6)H(7)N(2)O(2) (+)·Br(−), is isomorphous with 2-nitroanilinium chloride and contains an characteristic intramolecular N—H⋯O hydrogen bond, forming an S(6) motif. Intermolecular N—H⋯Br hydrogen bonds occur in the crystal structure. Two zigzag chains of C (2) (1)(4) motifs extend along the b-axis direction. These primary chain motifs intersect like a double helix structure, leading to R (6) (3)(12) ring motifs, which are arranged in tandem along the b axis. Hence, hydrophilic layers are generated at z = 1/4 and 3/4, which are sandwiched between alternate hydrophobic layers across z = 0 and 1/2. |
| format | Online Article Text |
| id | pubmed-3247429 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32474292012-01-04 2-Nitroanilinium bromide Anitha, R. Athimoolam, S. Bahadur, S. Asath Gunasekaran, M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(6)H(7)N(2)O(2) (+)·Br(−), is isomorphous with 2-nitroanilinium chloride and contains an characteristic intramolecular N—H⋯O hydrogen bond, forming an S(6) motif. Intermolecular N—H⋯Br hydrogen bonds occur in the crystal structure. Two zigzag chains of C (2) (1)(4) motifs extend along the b-axis direction. These primary chain motifs intersect like a double helix structure, leading to R (6) (3)(12) ring motifs, which are arranged in tandem along the b axis. Hence, hydrophilic layers are generated at z = 1/4 and 3/4, which are sandwiched between alternate hydrophobic layers across z = 0 and 1/2. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247429/ /pubmed/22220047 http://dx.doi.org/10.1107/S1600536811041948 Text en © Anitha et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Anitha, R. Athimoolam, S. Bahadur, S. Asath Gunasekaran, M. 2-Nitroanilinium bromide |
| title | 2-Nitroanilinium bromide |
| title_full | 2-Nitroanilinium bromide |
| title_fullStr | 2-Nitroanilinium bromide |
| title_full_unstemmed | 2-Nitroanilinium bromide |
| title_short | 2-Nitroanilinium bromide |
| title_sort | 2-nitroanilinium bromide |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247429/ https://www.ncbi.nlm.nih.gov/pubmed/22220047 http://dx.doi.org/10.1107/S1600536811041948 |
| work_keys_str_mv | AT anithar 2nitroaniliniumbromide AT athimoolams 2nitroaniliniumbromide AT bahadursasath 2nitroaniliniumbromide AT gunasekaranm 2nitroaniliniumbromide |