N,N′-[1,3-Phenylenebis(methyl­ene)]dibenzene­sulfonamide

The complete mol­ecule of the title compound, C(20)H(20)N(2)O(4)S(2), is generated by crystallographic twofold symmetry, with two C atoms lying on the rotation axis. The dihedral angle between the central benzene ring and the pendant ring is 68.42 (6)° and the dihedral angle between the pendant ring...

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Autores principales: Ejaz, Khan, Islam Ullah, Ahmad, Hira, Harrison, William T. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247431/
https://www.ncbi.nlm.nih.gov/pubmed/22220049
http://dx.doi.org/10.1107/S1600536811040694
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author Ejaz,
Khan, Islam Ullah
Ahmad, Hira
Harrison, William T. A.
author_facet Ejaz,
Khan, Islam Ullah
Ahmad, Hira
Harrison, William T. A.
author_sort Ejaz,
collection PubMed
description The complete mol­ecule of the title compound, C(20)H(20)N(2)O(4)S(2), is generated by crystallographic twofold symmetry, with two C atoms lying on the rotation axis. The dihedral angle between the central benzene ring and the pendant ring is 68.42 (6)° and the dihedral angle between the pendant rings is 45.11 (5)°. The torsion angles for the C—S—N—C and S—N—C—C fragments are −73.22 (15) and −150.45 (13)°, respectively. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds, generating corrugated (001) sheets. Aromatic π–π stacking [centroid–centroid separation = 3.8925 (12) and 3.9777 (12) Å] and weak C—H⋯O inter­actions also occur.
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spelling pubmed-32474312012-01-04 N,N′-[1,3-Phenylenebis(methyl­ene)]dibenzene­sulfonamide Ejaz, Khan, Islam Ullah Ahmad, Hira Harrison, William T. A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The complete mol­ecule of the title compound, C(20)H(20)N(2)O(4)S(2), is generated by crystallographic twofold symmetry, with two C atoms lying on the rotation axis. The dihedral angle between the central benzene ring and the pendant ring is 68.42 (6)° and the dihedral angle between the pendant rings is 45.11 (5)°. The torsion angles for the C—S—N—C and S—N—C—C fragments are −73.22 (15) and −150.45 (13)°, respectively. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds, generating corrugated (001) sheets. Aromatic π–π stacking [centroid–centroid separation = 3.8925 (12) and 3.9777 (12) Å] and weak C—H⋯O inter­actions also occur. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247431/ /pubmed/22220049 http://dx.doi.org/10.1107/S1600536811040694 Text en © Ejaz et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ejaz,
Khan, Islam Ullah
Ahmad, Hira
Harrison, William T. A.
N,N′-[1,3-Phenylenebis(methyl­ene)]dibenzene­sulfonamide
title N,N′-[1,3-Phenylenebis(methyl­ene)]dibenzene­sulfonamide
title_full N,N′-[1,3-Phenylenebis(methyl­ene)]dibenzene­sulfonamide
title_fullStr N,N′-[1,3-Phenylenebis(methyl­ene)]dibenzene­sulfonamide
title_full_unstemmed N,N′-[1,3-Phenylenebis(methyl­ene)]dibenzene­sulfonamide
title_short N,N′-[1,3-Phenylenebis(methyl­ene)]dibenzene­sulfonamide
title_sort n,n′-[1,3-phenylenebis(methyl­ene)]dibenzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247431/
https://www.ncbi.nlm.nih.gov/pubmed/22220049
http://dx.doi.org/10.1107/S1600536811040694
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