N,N′-[1,3-Phenylenebis(methylene)]dibenzenesulfonamide
The complete molecule of the title compound, C(20)H(20)N(2)O(4)S(2), is generated by crystallographic twofold symmetry, with two C atoms lying on the rotation axis. The dihedral angle between the central benzene ring and the pendant ring is 68.42 (6)° and the dihedral angle between the pendant ring...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247431/ https://www.ncbi.nlm.nih.gov/pubmed/22220049 http://dx.doi.org/10.1107/S1600536811040694 |
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author | Ejaz, Khan, Islam Ullah Ahmad, Hira Harrison, William T. A. |
author_facet | Ejaz, Khan, Islam Ullah Ahmad, Hira Harrison, William T. A. |
author_sort | Ejaz, |
collection | PubMed |
description | The complete molecule of the title compound, C(20)H(20)N(2)O(4)S(2), is generated by crystallographic twofold symmetry, with two C atoms lying on the rotation axis. The dihedral angle between the central benzene ring and the pendant ring is 68.42 (6)° and the dihedral angle between the pendant rings is 45.11 (5)°. The torsion angles for the C—S—N—C and S—N—C—C fragments are −73.22 (15) and −150.45 (13)°, respectively. In the crystal, molecules are linked by N—H⋯O hydrogen bonds, generating corrugated (001) sheets. Aromatic π–π stacking [centroid–centroid separation = 3.8925 (12) and 3.9777 (12) Å] and weak C—H⋯O interactions also occur. |
format | Online Article Text |
id | pubmed-3247431 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32474312012-01-04 N,N′-[1,3-Phenylenebis(methylene)]dibenzenesulfonamide Ejaz, Khan, Islam Ullah Ahmad, Hira Harrison, William T. A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The complete molecule of the title compound, C(20)H(20)N(2)O(4)S(2), is generated by crystallographic twofold symmetry, with two C atoms lying on the rotation axis. The dihedral angle between the central benzene ring and the pendant ring is 68.42 (6)° and the dihedral angle between the pendant rings is 45.11 (5)°. The torsion angles for the C—S—N—C and S—N—C—C fragments are −73.22 (15) and −150.45 (13)°, respectively. In the crystal, molecules are linked by N—H⋯O hydrogen bonds, generating corrugated (001) sheets. Aromatic π–π stacking [centroid–centroid separation = 3.8925 (12) and 3.9777 (12) Å] and weak C—H⋯O interactions also occur. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247431/ /pubmed/22220049 http://dx.doi.org/10.1107/S1600536811040694 Text en © Ejaz et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ejaz, Khan, Islam Ullah Ahmad, Hira Harrison, William T. A. N,N′-[1,3-Phenylenebis(methylene)]dibenzenesulfonamide |
title |
N,N′-[1,3-Phenylenebis(methylene)]dibenzenesulfonamide |
title_full |
N,N′-[1,3-Phenylenebis(methylene)]dibenzenesulfonamide |
title_fullStr |
N,N′-[1,3-Phenylenebis(methylene)]dibenzenesulfonamide |
title_full_unstemmed |
N,N′-[1,3-Phenylenebis(methylene)]dibenzenesulfonamide |
title_short |
N,N′-[1,3-Phenylenebis(methylene)]dibenzenesulfonamide |
title_sort | n,n′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247431/ https://www.ncbi.nlm.nih.gov/pubmed/22220049 http://dx.doi.org/10.1107/S1600536811040694 |
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