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Benzene-1,3-dicarboxylic acid–1,2-bis(4-pyridyl)ethene (1/1)
In the title compound, C(12)H(10)N(2)·C(8)H(6)O(4), the asymmetric unit contains two halves of 1,2-bis(4-pyridyl)ethene (bpe) molecules and one benzene-1,3-dicarboxylic acid (1,3-H(2)BDC) molecule. These bpe and 1,3-H(2)BDC molecules are linked by classical O—H⋯N hydrogen bonds, forming an ex...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247433/ https://www.ncbi.nlm.nih.gov/pubmed/22220051 http://dx.doi.org/10.1107/S1600536811043418 |
Sumario: | In the title compound, C(12)H(10)N(2)·C(8)H(6)O(4), the asymmetric unit contains two halves of 1,2-bis(4-pyridyl)ethene (bpe) molecules and one benzene-1,3-dicarboxylic acid (1,3-H(2)BDC) molecule. These bpe and 1,3-H(2)BDC molecules are linked by classical O—H⋯N hydrogen bonds, forming an extended one-dimensional zigzag chain. Each chain is further linked with neighboring ones by π–π interactions between the pyridine and aromatic rings [centroid–centroid distances = 3.9306 (15) Å] and the pyridine rings of pairs of symmetry-related molecules [centroid–centroid distances = 3.5751 (15), 3.7350 (15) and 3.6882 (15) Å], with the formation of a three-dimensional supramolecular framework. |
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