Benzene-1,3-dicarb­oxy­lic acid–1,2-bis­(4-pyrid­yl)ethene (1/1)

In the title compound, C(12)H(10)N(2)·C(8)H(6)O(4), the asymmetric unit contains two halves of 1,2-bis­(4-pyrid­yl)ethene (bpe) mol­ecules and one benzene-1,3-dicarb­oxy­lic acid (1,3-H(2)BDC) mol­ecule. These bpe and 1,3-H(2)BDC mol­ecules are linked by classical O—H⋯N hydrogen bonds, forming an ex...

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Detalles Bibliográficos
Autores principales: Liu, Dong, Li, Ni-Ya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247433/
https://www.ncbi.nlm.nih.gov/pubmed/22220051
http://dx.doi.org/10.1107/S1600536811043418
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author Liu, Dong
Li, Ni-Ya
author_facet Liu, Dong
Li, Ni-Ya
author_sort Liu, Dong
collection PubMed
description In the title compound, C(12)H(10)N(2)·C(8)H(6)O(4), the asymmetric unit contains two halves of 1,2-bis­(4-pyrid­yl)ethene (bpe) mol­ecules and one benzene-1,3-dicarb­oxy­lic acid (1,3-H(2)BDC) mol­ecule. These bpe and 1,3-H(2)BDC mol­ecules are linked by classical O—H⋯N hydrogen bonds, forming an extended one-dimensional zigzag chain. Each chain is further linked with neighboring ones by π–π inter­actions between the pyridine and aromatic rings [centroid–centroid distances = 3.9306 (15) Å] and the pyridine rings of pairs of symmetry-related mol­ecules [centroid–centroid distances = 3.5751 (15), 3.7350 (15) and 3.6882 (15) Å], with the formation of a three-dimensional supra­molecular framework.
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spelling pubmed-32474332012-01-04 Benzene-1,3-dicarb­oxy­lic acid–1,2-bis­(4-pyrid­yl)ethene (1/1) Liu, Dong Li, Ni-Ya Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(10)N(2)·C(8)H(6)O(4), the asymmetric unit contains two halves of 1,2-bis­(4-pyrid­yl)ethene (bpe) mol­ecules and one benzene-1,3-dicarb­oxy­lic acid (1,3-H(2)BDC) mol­ecule. These bpe and 1,3-H(2)BDC mol­ecules are linked by classical O—H⋯N hydrogen bonds, forming an extended one-dimensional zigzag chain. Each chain is further linked with neighboring ones by π–π inter­actions between the pyridine and aromatic rings [centroid–centroid distances = 3.9306 (15) Å] and the pyridine rings of pairs of symmetry-related mol­ecules [centroid–centroid distances = 3.5751 (15), 3.7350 (15) and 3.6882 (15) Å], with the formation of a three-dimensional supra­molecular framework. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247433/ /pubmed/22220051 http://dx.doi.org/10.1107/S1600536811043418 Text en © Liu and Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Dong
Li, Ni-Ya
Benzene-1,3-dicarb­oxy­lic acid–1,2-bis­(4-pyrid­yl)ethene (1/1)
title Benzene-1,3-dicarb­oxy­lic acid–1,2-bis­(4-pyrid­yl)ethene (1/1)
title_full Benzene-1,3-dicarb­oxy­lic acid–1,2-bis­(4-pyrid­yl)ethene (1/1)
title_fullStr Benzene-1,3-dicarb­oxy­lic acid–1,2-bis­(4-pyrid­yl)ethene (1/1)
title_full_unstemmed Benzene-1,3-dicarb­oxy­lic acid–1,2-bis­(4-pyrid­yl)ethene (1/1)
title_short Benzene-1,3-dicarb­oxy­lic acid–1,2-bis­(4-pyrid­yl)ethene (1/1)
title_sort benzene-1,3-dicarb­oxy­lic acid–1,2-bis­(4-pyrid­yl)ethene (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247433/
https://www.ncbi.nlm.nih.gov/pubmed/22220051
http://dx.doi.org/10.1107/S1600536811043418
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AT liniya benzene13dicarboxylicacid12bis4pyridylethene11

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